Multi-ply Paper Bonding with Microfibrillated Cellulose

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Solution Overview

Problem

Existing methods for producing multi-ply cartonboards face challenges in minimizing cracking and delamination tendencies while maintaining mechanical strength and stiffness, often requiring increased grammage or refining, which can increase costs and reduce bending stiffness.

Innovation Solution

Incorporating microfibrillated cellulose between the plies of a paper or board product, along with starch, to enhance bonding and reduce delamination and cracking, allowing for more flexible and stronger inter-ply bonds.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If starch is sprayed between the plies before couching, then bonding between plies is improved, but cracking tendency increases due to un-stretching bonds

Engineering Contradiction:
Improvebond strength between pliesVSAvoidcracking tendency
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the bonding agent by replacing starch with a polyamide polymer containing carboxylic acid groups. This parameter change transforms the bonding mechanism from rigid starch bonds to flexible polymer bonds that can stretch, thereby maintaining bond strength while reducing cracking tendency during creasing operations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite bonding approach by combining polyamide polymer with optional additives such as metal salts (calcium, magnesium, aluminum) or oxidizing agents. This composite material system provides both strong bonding and flexibility, resolving the contradiction between bond strength and cracking resistance.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If top and bottom ply grammage is increased to prevent cracking, then cracking tendency is reduced, but cost increases and bending stiffness decreases

Engineering Contradiction:
Improvecracking tendencyVSAvoidcost and bending stiffness
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent introduces a polyamide polymer as an intermediary bonding agent between the plies. This mediator provides strong adhesion and flexibility, allowing the use of lower grammage top and bottom plies while still preventing cracking. The intermediary absorbs the stress during creasing, eliminating the need for excessive ply thickness.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Strength

If refining of middle ply is increased to increase fines content, then bonding between plies is improved, but caliper decreases and bending stiffness index is reduced

Engineering Contradiction:
Improvebonding between pliesVSAvoidcaliper and bending stiffness
Core Design Contradiction:
StrengthVSShape

Solution Approach 1:

The patent replaces the mechanical refining process with a chemical bonding approach using polyamide polymer. Instead of mechanically increasing fines content through refined pulp, the chemical polymer provides bonding between plies. This substitution maintains caliper and bending stiffness while achieving strong inter-ply bonding.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process increases the bond strength between plies, reduces delamination and cracking, and allows for reduced grammage and refining, leading to cost savings and improved bending stiffness without compromising mechanical properties.

Implementation Method 1

adding starch together with the microfibrillated cellulose to at least one surface of a ply... attaching the second ply to the first ply so that the added microfibrillated cellulose and starch are located in between the first and second plies

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentEP2496766B2Process for the production of a paper or board product and a paper or board produced according to the process
Publication Date: 2024.05.15 STORA ENSO OYJ

AI summary

The present invention relates to a process for the production of a paper or paperboard comprising at least two plies wherein microfibrillated cellulose is added to the surface of a first ply and the other ply is attached to the first ply so that the microfibrillated cellulose located in between the plies. The invention further relates to a paper or board produced according to the method.