Paper Nanocomposite Water Leak Sensor

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Solution Overview

Problem

Existing water leak detection systems are inefficient due to expensive and unreliable sensors that fail to accurately detect leaks in a timely manner, often requiring human intervention and suffering from material degradation in aqueous environments, leading to significant water loss and economic losses.

Innovation Solution

A paper nanocomposite is developed by combining lignocellulosic pulp fibers, cellulose nanofibrils, and carbon nanotubes with surfactants, forming a stable and durable sensing material that can reliably detect water leaks through changes in electrical resistance, enabling rapid and cost-effective leak detection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional polymer-based sensors are used for water leak detection, then the sensors can detect water, but they suffer from material degradation in aqueous environments leading to inconsistent signals and reduced reliability

Engineering Contradiction:
Improvesensor reliabilityVSAvoidsensor lifespan
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent uses a composite material system consisting of cellulose nanofibrils (CNFs) as the matrix, carbon nanotubes (CNTs) as conductive fillers, and lignin or cationic surfactants as dispersants. This composite structure provides both mechanical integrity and electrical conductivity while resisting degradation in aqueous environments, thereby improving reliability and extending sensor lifespan.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical and physical parameters of the sensor materials by functionalizing carbon nanotubes with hydroxyl groups and using specific dispersants (lignin or cationic surfactants) to enhance compatibility with the cellulose matrix. These parameter changes improve the stability and durability of the sensor in water exposure.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If existing sensor technologies are deployed for leak detection, then water leaks can be detected, but the systems are expensive and require human intervention for confirmation

Engineering Contradiction:
Improveleak detection accuracyVSAvoidsystem complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The paper nanocomposite sensor provides self-service by automatically detecting water leaks through changes in electrical resistance and generating measurable signals that can be directly processed by simple electronic circuits. The sensor eliminates the need for complex inference algorithms and human intervention, as the cellulose-CNT composite directly transduces water presence into electrical signals.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces complex mechanical and electronic sensor systems with a simple paper-based nanocomposite that uses the intrinsic properties of cellulose and carbon nanotubes to detect water. This substitution simplifies the overall system while maintaining or improving detection precision.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If conventional electrode formation methods are used on paper surfaces, then electrodes can be created, but the electrode films are non-uniform and have low accuracy affecting device performance

Engineering Contradiction:
Improveelectrode uniformityVSAvoidfabrication difficulty
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent utilizes the porous structure of paper and the network formation capability of cellulose nanofibrils to create uniform distributions of carbon nanotubes throughout the matrix. The porous network allows for even dispersion and consistent electrical properties across the electrode surface, improving manufacturing precision.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent uses lignin or cationic surfactants as intermediary agents to mediate between the hydrophobic carbon nanotubes and the hydrophilic cellulose matrix. These intermediaries ensure uniform dispersion and stable adhesion of CNTs to the paper surface, resulting in consistent electrode films that are easier to manufacture with high precision.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Speed

If non-polar materials are used for water sensing, then the materials can be employed in sensor construction, but they exhibit weak or slow responses to water

Engineering Contradiction:
Improvewater response speedVSAvoidsensing performance
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent changes the polar character of the sensor materials by using hydroxyl-functionalized carbon nanotubes and hydrophilic dispersants (lignin or cationic surfactants) that enhance water affinity. This parameter change from non-polar to polar/hydrophilic characteristics enables fast and reliable water response.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite of hydrophilic cellulose nanofibrils with functionalized carbon nanotubes creates a material system that combines fast water response with stable electrical conductivity. The cellulose matrix provides hydrophilicity for rapid water uptake while the CNT network maintains electrical signal integrity.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The paper nanocomposite exhibits high sensitivity to water, maintaining performance over multiple cycles and long-term use, allowing for efficient detection of water leaks and reducing water loss and associated costs.

Implementation Method 1

carbon nanotubes with surfactants, forming a stable and durable sensing material that can reliably detect water leaks through changes in electrical resistance

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

Given its bio-renewable and hygroscopic nature, cellulosic paper provides an excellent platform for building sustainable and affordable water sensors

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

a first liquid suspension including lignocellulosic pulp fibers, cellulose nanofibrils, carbon nanotubes, and a cationic surfactant; continuously adding a second liquid suspension to the first liquid suspension to provide a slurry, the second liquid suspension including lignocellulosic pulp fibers, cellulose nanofibrils, carbon nanotubes, and an anionic surfactant

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentUS20230407570A1Electrically conductive smart papers
Publication Date: 2023.12.21 UNIV OF WASHINGTON
  • US20230407570A1 patent drawing
  • US20230407570A1 patent drawing
  • US20230407570A1 patent drawing

AI summary

The present disclosure describes a method for preparing a paper nanocomposite, including: continuously providing a first suspension that includes lignocellulosic pulp fibers, cellulose nanofibrils, carbon nanotubes, and a cationic surfactant; continuously adding a second suspension to the first suspension to provide a slurry, the second suspension includes lignocellulosic pulp fibers, cellulose nanofibrils, carbon nanotubes, and an anionic surfactant; depositing the slurry comprising the first and second suspensions onto the substrate; and dewatering the slurry to form the paper nanocomposite.