Parallel Distillation Columns for Aromatics Energy Conservation

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Solution Overview

Problem

Aromatics complexes, particularly those producing xylene isomers, are substantial consumers of energy in distillation operations, leading to high processing costs and carbon emissions, with existing separation methods being inefficient in conserving energy.

Innovation Solution

The implementation of a distillation process using two columns operating at different pressures, where the overhead stream from a higher-pressure column provides heat to the reboiler of a lower-pressure column, enhancing heat transfer and energy efficiency while preventing degradation of heavy components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional distillation operations are used to separate C8 aromatics from heavy aromatics, then separation is achieved, but energy consumption is high

Engineering Contradiction:
Improveenergy consumptionVSAvoidseparation efficiency
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The patent combines multiple distillation columns into an integrated system where columns operate at different pressures and are thermally coupled. The overhead vapor from the high-pressure column is directly used to reboil the low-pressure column, merging the separation function with energy recovery in a single integrated process flow.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent changes the operating pressure parameter across different columns in the distillation system. By operating columns at different pressures (high-pressure and low-pressure columns), the system creates temperature differences that enable thermal coupling and energy recovery between columns, reducing overall energy consumption.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If high energy input is applied to distillation operations, then separation performance improves, but carbon emissions increase

Engineering Contradiction:
Improveseparation performanceVSAvoidcarbon emissions
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent converts the waste heat energy that would otherwise be lost from the high-pressure column into a useful resource by using it to reboil the low-pressure column. This transforms potential energy waste (harm) into beneficial thermal energy for driving the separation process, thereby reducing the need for additional fossil fuel combustion and associated carbon emissions.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Quantity of substance

If existing separation methods are used, then product recovery is achieved, but energy efficiency is low

Engineering Contradiction:
Improveproduct recoveryVSAvoidenergy efficiency
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The high-pressure column essentially serves itself by providing its own overhead vapor as the heating medium for the low-pressure column's reboiler. This self-service arrangement eliminates the need for external steam or utility energy for at least part of the reboiling requirement, significantly improving energy efficiency while maintaining product recovery.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in significant energy savings without compromising product yield, reducing the risk of equipment fouling, and addressing carbon emission concerns by optimizing heat exchange between columns.

Implementation Method 1

the overhead stream from a higher-pressure column provides heat to the reboiler of a lower-pressure column, enhancing heat transfer and energy efficiency

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Data Source

PatentEP2609058B1Energy conservation in heavy-hydrocarbon distillation
Publication Date: 2019.07.24 UOP LLC
  • EP2609058B1 patent drawingFigure 1
  • EP2609058B1 patent drawingFigure 2
  • EP2609058B1 patent drawingFigure 3

AI summary

An aromatics complex producing one or more xylene isomers offers a large number of opportunities to conserve energy by heat exchange within the complex. One previously unrecognized opportunity is through providing two parallel distillation columns operating at different pressures to separate C8 aromatics from C9+ aromatics. The parallel columns offer additional opportunities to conserve energy within the complex.