Parallel Resistor Anode Structure for Copper Electrowinning

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Solution Overview

Problem

In metal electrodeposition plants, dendritic formations during non-ferrous metal electrowinning can cause uneven metal deposition, electrical short circuits, and damage to electrodes, posing safety risks and efficiency issues, particularly with modern anode materials like titanium, which are prone to extensive and irreversible damage from such short circuits.

Innovation Solution

An anodic apparatus with anodic panels connected through a plurality of resistors in parallel, which slows down dendritic growth and limits current in case of short circuits, using resistors with specific resistance values and geometric characteristics to manage current flow and minimize damage, while maintaining operational efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If automatic monitoring systems with electronic components are used to control current, then dendritic growth can be monitored, but the system becomes complex and expensive and reliability decreases due to acid environment and high current densities

Engineering Contradiction:
Improvereliability of monitoring systemVSAvoidcomplexity of monitoring system
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts the monitoring function from complex electronic systems and implements it through simple ohmic resistors that inherently limit current through their resistance property. This removes fragile electronic components from the acidic environment while maintaining monitoring capability through basic electrical resistance principles.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses simple, inexpensive ohmic resistors instead of complex electronic monitoring systems. These resistors are robust, cheap components that can withstand the harsh electrolytic environment without requiring protection or maintenance, effectively serving as disposable protective elements.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If resistors are placed in series, then current limiting is achieved, but voltage drop increases and power consumption rises

Engineering Contradiction:
Improveprotection against short circuitsVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent divides the current limiting function into multiple parallel resistor paths instead of using a single series resistor. This segmentation allows current to be distributed across multiple low-resistance paths, achieving protection while minimizing total voltage drop and power loss compared to a single high-resistance series element.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses multiple resistors with individual resistance values that are higher than the optimal single value, but when connected in parallel, the equivalent resistance becomes low enough to minimize power loss while still providing sufficient current limiting protection during short circuit conditions.

Inventive Principle:
Principle #16Partial or excessive action

3Reliability

If resistors with higher resistance values are used, then current limiting improves, but voltage drop increases reducing operating efficiency

Engineering Contradiction:
Improveprotection against dendrite damageVSAvoidoperating efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent segments the protection function across multiple parallel resistors, each with higher individual resistance values that provide adequate current limiting, while the parallel configuration maintains low equivalent resistance to minimize voltage drop during normal operation, thus preserving operating efficiency.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively slows down dendritic growth for over 24 hours, reduces damage from short circuits, and maintains plant efficiency by controlling current flow through selective resistor paths, thus protecting the anodic panel and ensuring safe and uniform metal deposition.

Implementation Method 1

at least one anodic panel and at least one electrical current distribution structure electrically connected together by means of a plurality of resistors placed in parallel

Methodology Applied
Scientific EffectElectrical Resistance: Electrical Resistance

Data Source

PatentUS11136684B2Electrode structure provided with resistors
Publication Date: 2021.10.05 INDUSTRIE DE NORA SPA
  • US11136684B2 patent drawing
  • US11136684B2 patent drawing
  • US11136684B2 patent drawing

AI summary

The invention relates to an electrode which can be employed in the cells of plants for the electrolytic extraction of copper and other non-ferrous metals from ionic solutions. The electrode consists of an apparatus comprising at least one anodic panel for the evolution of oxygen or chlorine connected through a plurality of resistors in parallel to at least one distribution structure for electrical current. The panel may optionally exhibit areas of electrical discontinuity. The invention also relates to an electrolyser using the electrode described above.