Parallel Xylene Columns for Energy Conservation

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Solution Overview

Problem

Aromatics complexes, particularly those producing xylene isomers, are substantial consumers of energy in distillation operations, leading to high processing costs and carbon emissions, with a need for energy conservation in separating xylenes from heavy aromatics.

Innovation Solution

A process involving two xylene columns operating at different pressures to separate C8 aromatics from C9-and-heavier aromatics, with heat exchange between columns to optimize energy usage, and a para-xylene separation process using adsorption and desorbent recovery to enhance energy efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional distillation operations are used to separate xylenes from heavy aromatics, then separation is achieved, but energy consumption is excessive

Engineering Contradiction:
Improveenergy consumptionVSAvoidseparation efficiency
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The distillation process is divided into multiple columns operating at different pressures. The first column operates at lower pressure to separate C8 aromatics from C9+ heavy aromatics, while the second column operates at higher pressure to further separate xylene isomers. This segmentation allows each column to operate at optimal conditions, reducing overall energy consumption while maintaining separation efficiency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the pressure parameter across different distillation columns to optimize energy efficiency. By operating the first column at lower pressure and the second column at higher pressure, the system achieves better separation with reduced energy input. The pressure gradient enables heat exchange between columns, further reducing energy losses.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If multiple distillation columns operate at different pressures to improve separation, then separation efficiency increases, but process complexity increases

Engineering Contradiction:
Improveseparation efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

Multiple distillation columns are merged into an integrated system with shared heat exchange networks. The overhead stream from the second column (higher pressure) exchanges heat with the reboiler of the first column (lower pressure), creating a coupled system that reduces overall energy consumption. This merging of functions reduces the need for separate energy input systems.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The distillation columns are designed to perform multiple functions: separation of different aromatic fractions, heat exchange with each other, and production of various xylene isomer streams. The system handles multiple separation tasks within a unified process architecture, reducing the need for entirely separate processing units.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Loss of energy

If heat exchange between columns is implemented to save energy, then energy consumption decreases, but equipment requirements increase

Engineering Contradiction:
Improveenergy consumptionVSAvoidequipment requirements
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

Heat exchange surfaces act as intermediaries between the overhead stream of the second column and the reboiler of the first column. These heat exchange equipment enable energy transfer between the two columns, allowing the hotter overhead stream to preheat the cooler reboiler stream, thereby reducing the energy required for vaporization in the first column.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces energy consumption and processing costs while addressing carbon emissions by optimizing heat exchange and separation efficiency in aromatics processing.

Implementation Method 1

an overhead stream from the second xylene column exchanges heat with a reboiler of the first xylene column

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

distilling the at least one higher-boiling feed stream in a first xylene column at a first pressure to separate a first C 8 -aromatics stream from a first C 9 -and-heavier aromatics stream

Methodology Applied
Scientific EffectDistillation: Distillation

Implementation Method 3

recovering para-xylene from one or both of the first and second C 8 -aromatics streams by injecting the one or both C 8 -aromatics streams and a desorbent stream into an adsorption process

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2609057B1Energy conservation in heavy-hydrocarbon distillation
Publication Date: 2019.02.20 UOP LLC
  • EP2609057B1 patent drawingFigure 1
  • EP2609057B1 patent drawingFigure 2
  • EP2609057B1 patent drawingFigure 2A

AI summary

An aromatics complex producing one or more xylene isomers offers a large number of opportunities to conserve energy by heat exchange within the complex. One previously unrecognized opportunity is through providing two parallel distillation columns operating at different pressures to separate C8 aromatics from C9+ aromatics. The parallel columns offer additional opportunities to conserve energy within the complex through heat exchange in associated xylene recovery facilities.