Parallel Xylene Columns for Energy Conservation

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Solution Overview

Problem

Aromatics complexes, particularly those producing xylene isomers, are substantial consumers of energy in distillation operations, leading to high processing costs and carbon emissions, with a need for energy conservation in separating xylenes from heavy aromatics.

Innovation Solution

A process involving two xylene columns operating at different pressures to separate C8 aromatics from C9-and-heavier aromatics, with heat exchange between columns to optimize energy usage, and an adsorption process to recover individual xylene isomers using a desorbent stream, enhancing energy efficiency and reducing emissions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If a single distillation column is used to separate C8 aromatics from C9-and-heavier aromatics, then the process is simpler, but energy consumption is high and equipment fouling occurs

Engineering Contradiction:
Improveenergy consumptionVSAvoidprocess complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The distillation process is divided into two separate columns: a first distillation column operating at a first pressure to separate C8 aromatics from C9-and-heavier aromatics, and a second distillation column operating at a second pressure to further separate the C8 stream. This segmentation allows each column to operate under optimized conditions, reducing energy consumption and preventing fouling while maintaining separation effectiveness.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention employs different operating pressures in the two distillation columns to optimize separation and energy efficiency. The first column operates at a first pressure while the second column operates at a second pressure, allowing each column to function at its optimal pressure point for minimal energy consumption and maximal separation efficiency.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If heat exchange between columns is implemented, then energy savings are achieved, but process complexity increases

Engineering Contradiction:
Improveenergy lossVSAvoidheat exchange system complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The invention merges the thermal energy streams by having the overhead stream from the second distillation column provide heat to the reboiler of the first distillation column. This heat integration combines the cooling需求 of one stream with the heating需求 of another, significantly reducing external energy input requirements while using existing process streams.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The system uses its own internal heat streams to satisfy thermal requirements. The overhead stream from the second column serves as the heat source for the first column's reboiler, allowing the distillation system to partially self-service its own thermal needs without requiring additional external energy input.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach achieves significant energy savings by optimizing heat transfer and reducing energy consumption in distillation processes, while maintaining product yield and avoiding equipment fouling, thus addressing the high energy usage and emissions in aromatics complex operations.

Implementation Method 1

an overhead stream from the second xylene column exchanges heat with a reboiler of the first xylene column

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

An overhead stream of the first xylene column of step (a) provides heat to a reboiler of the extract column

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 3

injecting the one or both C 8 -aromatics streams and a desorbent stream into an adsorption process to obtain a first mixture comprising the individual xylene isomer and desorbent

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

separate the first mixture of step (b) by distilling the first mixture in an extract column at an operating pressure of at least 300 kPa to produce a stream comprising the individual xylene isomer and a desorbent stream

Methodology Applied
Scientific EffectDistillation: Distillation

Data Source

PatentEP2609059B1Energy conservation in heavy-hydrocarbon distillation
Publication Date: 2018.04.18 UOP LLC
  • EP2609059B1 patent drawingFigure 1
  • EP2609059B1 patent drawingFigure 2
  • EP2609059B1 patent drawingFigure 3

AI summary

An aromatics complex producing one or more xylene isomers offers a large number of opportunities to conserve energy by heat exchange within the complex. One previously unrecognized opportunity is through providing two parallel distillation columns operating at different pressures to separate C8 aromatics from C9+ aromatics. The parallel columns offer additional opportunities to conserve energy within the complex through heat exchange in associated xylene recovery facilities.