Particulate Nonionic Synthetic Associative Thickener for Paint Formulations

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The existing delivery of nonionic synthetic associative thickener (NSAT) rheology modifiers in aqueous solutions leads to high water content, increased shipping costs, environmental impact, limited process design flexibility, and undesirable viscosity suppressants in waterborne paint formulations, along with challenges in product stability and storage due to phase separation.

Innovation Solution

A particulate product comprising a nonionic synthetic associative thickener (NSAT) rheology modifier and a dissolution promotion water-soluble additive, such as sugars like sucrose, fructose, or glucose, which reduces shipping costs, storage volume, and packaging costs, and allows for tailored rheology and incorporation into paint formulations without the need for viscosity suppressants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If NSAT rheology modifiers are delivered as aqueous solutions, then they provide superior rheological characteristics, but they increase shipping costs and environmental impact due to high water content

Engineering Contradiction:
Improverheological performanceVSAvoidshipping cost
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent extracts the active NSAT rheology modifier from the aqueous solution delivery system and provides it as a concentrated form (e.g., paste or solid). This removes the unnecessary water component that increases shipping costs and environmental impact while preserving the rheological performance benefits of NSAT when used at appropriate concentrations in the final paint formulation.

Inventive Principle:
Principle #2Taking out (Extraction)

2Ease of manufacture

If aqueous solutions are used to deliver NSAT, then dissolution occurs, but packaging costs increase and disposal of packaging materials creates negative environmental consequences

Engineering Contradiction:
ImprovedissolutionVSAvoidpackaging cost
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent changes the physical state and concentration parameters of the NSAT delivery system from dilute aqueous solution to concentrated paste or solid form. This parameter change eliminates the need for large-volume packaging while maintaining the ability to dissolve and disperse the NSAT effectively in the paint formulation through controlled addition and mixing processes.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If water is used to deliver NSAT rheology modifiers, then the active solid contents range from 17 to 30 wt%, but this reduces the amount of available free water for other ingredients

Engineering Contradiction:
Improveactive solid contentVSAvoidprocess design flexibility
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The patent applies preliminary action by pre-concentrating the NSAT rheology modifier into a paste or solid form with high active solid content. This preliminary concentration step allows the NSAT to be added to the paint formulation without consuming valuable free water, thereby preserving process design flexibility and enabling better control over the water balance and ingredient compatibility in the final formulation.

Inventive Principle:
Principle #10Preliminary action

4Ease of operation

If viscosity suppressants are added to handle NSAT products, then the product becomes more readily handled, but VOCs are introduced which are undesirable from health and environmental standpoints

Engineering Contradiction:
ImprovehandlingVSAvoidVOC content
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The patent replaces persistent harmful substances (VOC-based viscosity suppressants) with a temporary, benign alternative (water or alcohol-based viscosity control). The water or alcohol serves as a short-living, easily evaporated or dispersed medium that provides temporary viscosity reduction during handling and application, then disappears without leaving harmful residues in the final paint product.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The particulate form significantly improves dissolution rates, reduces environmental impact, and enhances process flexibility by allowing for easier handling and storage, while maintaining or improving paint performance characteristics.

Implementation Method 1

A particulate product comprising a nonionic synthetic associative thickener (NSAT) rheology modifier and a dissolution promotion water soluble additive

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentEP2736946B1Readily dissolvable solid nonionic synthetic associative thickener with dissolution promotion water soluble additive
Publication Date: 2018.09.26 HERCULES LLC
  • EP2736946B1 patent drawingFigure 1
  • EP2736946B1 patent drawingFigure 2
  • EP2736946B1 patent drawingFigure 3

AI summary

The presently disclosed and claimed inventive concept(s) relates to a particulate product. The particulate product comprises a nonionic synthetic associative thickener NSAT) rheology modifier and a dissolution promotion water soluble additive. The NSAT rheology modifier is selected from the group consisting of hydrophobically-modified ethoxyfated urethane (HEIJR), hydrophobically-modified polyethylene glycol (HMPEG), and hydrophobically-modified polyacetal-polvether (HMPAPE). The particulate product is incorporated into a waterborne paint formula.