Passivating Metallic Components to Reduce Fouling in Oil Recovery

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Solution Overview

Problem

In oil recovery systems like SAGD, metallic components face fouling due to hydrocarbon exposure, leading to frequent and costly cleaning and maintenance, as conventional methods are ineffective in preventing corrosion and subsequent fouling.

Innovation Solution

Passivation of metallic components using agents like hydroxyethylidene-diphosphonic acid, sodium erythorbate, and sodium nitrate to form a protective film, which can be applied during system operation or offline, reducing corrosion and fouling by forming a stable, non-reactive surface layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cleaning methods are used, then fouling is removed temporarily, but corrosion and fouling recur quickly requiring frequent maintenance

Engineering Contradiction:
Improveequipment reliabilityVSAvoiddowntime for cleaning
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent applies preliminary action by passivating metallic components with chemical agents (such as phosphates, silicates, or chromates) before they are exposed to hydrocarbon environments. This pre-treatment creates a protective layer that prevents corrosion and reduces fouling accumulation, thereby extending the time between cleaning operations and improving overall equipment reliability without requiring frequent maintenance shutdowns.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If the system remains online continuously, then productivity is maintained, but fouling accumulates requiring offline cleaning

Engineering Contradiction:
Improvesystem productivityVSAvoidhydrocarbon fouling
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces chemical passivating agents as intermediaries between the metallic components and the hydrocarbon environment. These agents form protective films on metal surfaces that act as barriers, preventing direct contact between hydrocarbons and the metal. This intermediary layer reduces fouling accumulation during continuous operation, allowing the system to maintain productivity while minimizing the harmful effects of hydrocarbon exposure.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If frequent cleaning is performed, then fouling is removed, but maintenance costs and labor intensity increase

Engineering Contradiction:
Improvefouling accumulationVSAvoidmaintenance cost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent changes the chemical parameters of the metal surface through passivation treatment, transforming the surface properties to be more resistant to fouling. By modifying surface chemistry (e.g., creating oxide layers or applying chemical coatings), the patent reduces the adhesion of hydrocarbon deposits, thereby decreasing fouling accumulation and reducing the frequency and cost of maintenance operations.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The passivation method significantly reduces equipment fouling, minimizing downtime and maintenance costs by preventing corrosion and hydrocarbon accumulation on metallic surfaces, thereby enhancing the efficiency and longevity of heat exchangers and other components.

Implementation Method 1

The passivating of the metallic component may comprise promoting the formation of a passivating film on the surface of the metallic component to prevent corrosion

Methodology Applied
Scientific EffectPassivation: Oxidation

Implementation Method 2

contacting the metallic component with a caustic solution while the oil recovery system is online

Methodology Applied
Scientific EffectChemical dissolution: Solvation

Data Source

PatentUS9382629B2Preventing equipment fouling via corrosion reduction
Publication Date: 2016.07.05 CHEMTREAT INC
  • US9382629B2 patent drawing

AI summary

An embodiment prevents equipment fouling (deposition of unwanted material) in an oil recovery system via implementing passivation of metallic components. By preventing or at least slowing or inhibiting corrosion of equipment or components via passivation, such as passivating heat exchangers, metallic piping, and the like, an embodiment in turn reduces fouling thereof. Other embodiments are described and claimed.