Pasty Composition for High Aspect Ratio 3D Structures

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Solution Overview

Problem

Current methods for manufacturing three-dimensional structures with high aspect ratios for electrochemical and electronic components are limited by the inability to achieve sufficient layer thickness and stability, leading to structural defects and increased production costs due to the limitations of printing technologies like silk screen and tampon printing.

Innovation Solution

A pasty composition comprising a heterogeneous mixture of powdery solids, organic polymers, solvents with controlled evaporation rates, and additives that allows for the formation of self-supporting structures with high aspect ratios through controlled evaporation and heat treatment, enabling precise shaping and mechanical stability before sintering.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If silk screen printing or tampon printing is used to manufacture functional layers, then manufacturing cost is reduced, but aspect ratio and layer thickness are limited

Engineering Contradiction:
Improvemanufacturing costVSAvoidaspect ratio
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent modifies the physical-chemical parameters of the paste composition by incorporating specific binders, solvents, and additives that control viscosity and drying behavior. This enables the paste to maintain stability during printing while achieving higher layer thicknesses and aspect ratios that would be impossible with conventional printing pastes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite paste formulations combining conductive powders (silver, copper, or electrically conductive ceramics) with specially designed polymer binders and solvent systems. This composite structure allows the paste to exhibit both printability and the mechanical strength needed to maintain high aspect ratios without collapsing during drying and sintering

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If higher layer thickness is achieved to increase aspect ratio, then structural stability deteriorates due to collapse and formation of recesses

Engineering Contradiction:
Improveaspect ratioVSAvoidstructural stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent applies preliminary protective actions by formulating the paste with binders and additives that create a stable green body structure before sintering. The paste composition is designed to maintain structural integrity during the critical drying phase, preventing collapse and recess formation that would otherwise occur with thick layers

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention changes the rheological and drying parameters of the paste through careful selection of solvent evaporation rates and binder properties. This controlled parameter change allows thick layers to be deposited and maintained in a stable configuration throughout the drying and sintering processes

Inventive Principle:
Principle #35Parameter changes

3Shape

If cutting machining is performed on sintered structures, then final shape is achieved, but material damage and structure failure occur due to brittleness

Engineering Contradiction:
Improvefinal shapeVSAvoidstructure integrity
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent performs preliminary shaping operations on the green body (unsintered) structure while it is still in a ductile, machinable state. This preliminary action allows complex three-dimensional shapes to be formed before sintering, eliminating the need for subsequent machining of brittle sintered parts and preventing structure failure

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention replaces post-sintering mechanical machining with pre-sintering shaping operations. By performing formative operations while the material is in its green, ductile state rather than after sintering when it is brittle, the process eliminates the harmful mechanical stresses that cause cracking and failure

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Ease of operation

If conventional paste formulations are used, then application is simple, but mechanical properties of dried paste are insufficient requiring high processing effort

Engineering Contradiction:
Improveapplication simplicityVSAvoidprocessing effort
Core Design Contradiction:
Ease of operationVSEase of manufacture

Solution Approach 1:

The patent uses composite paste formulations with specially designed polymer binders and additives that provide both ease of application and superior mechanical properties in the dried green body. The composite nature of the paste allows it to be easily printed while forming a structurally sound layer that requires minimal post-processing

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention modifies the physical-chemical parameters of the paste composition to achieve optimal balance between printability and mechanical strength. By controlling viscosity, solvent evaporation rate, and binder properties, the paste applies easily but dries to a mechanically robust green body that resists damage during handling and requires minimal machining effort

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the creation of structures with improved mechanical properties and aspect ratios, reducing the risk of structural defects and production costs by allowing for precise shaping and stable formation of functional layers with enhanced adhesion and reduced material removal forces.

Implementation Method 1

a first solvent C1 having a boiling temperature at which an evaporation of the first solvent C1 takes place

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

in a heat treatment in which a sintering of a solid contained in a pasty composition takes place

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS11034848B2Paste-like composition and method for producing three-dimensional structures or structural elements on substrate surfaces
Publication Date: 2021.06.15 FRAUNHOFER GESELLSCHAFT ZUR FORDERUNG DER ANGEWANDTEN FORSCHUNG EV

AI summary

A pasty composition for the manufacture of three-dimensional structures or structural elements on the surface of a substrate is formed together with a polymer as an organic component B1, and a powdery material that makes up a proportion of solid in the range of 60 mass % to 95 mass % in the composition, andat least two mutually different solvents C1 and C2 that form a solvent mixture. A first solvent C1 has a boiling temperature here that is lower than the boiling temperature of the further solvent or solvents C2.