Pattern-Forming Method for Lithography

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Solution Overview

Problem

Current methods for miniaturizing patterns in lithography processes, such as those used in semiconductor and liquid crystal device manufacturing, face challenges in achieving precise and smooth miniaturization while maintaining etching resistance and pattern uniformity.

Innovation Solution

A pattern-forming method involving the formation of a base pattern on a substrate, followed by application of a first composition containing a polymer with interacting groups, contact with a highly polar solvent, filling with a second composition capable of directed self-assembly, permitting phase separation, and removing phases to create a miniaturized pattern, which is then used as a mask for etching.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of moving object

If directed self-assembly of block copolymer is used to form finer patterns, then pattern miniaturization is achieved, but pattern roughness increases and Critical Dimension Uniformity deteriorates

Engineering Contradiction:
Improvepattern sizeVSAvoidCritical Dimension Uniformity
Core Design Contradiction:
Length of moving objectVSManufacturing precision

Solution Approach 1:

The patent divides the pattern formation process into multiple stages: first forming a base pattern with larger dimensions, then using directed self-assembly of block copolymer to create smaller features within the base pattern regions. This segmentation allows different parts of the structure to be optimized independently - the base pattern provides structural integrity while the self-assembled regions provide fine feature definition, thereby achieving miniaturization without sacrificing CDU

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies different materials and processes to different regions of the substrate. The base pattern regions use conventional lithography materials and processes, while the miniaturized pattern regions use block copolymer directed self-assembly. This local differentiation allows each region to have optimal properties for its specific function, resolving the contradiction between overall pattern size and local feature uniformity

Inventive Principle:
Principle #3Local quality

2Manufacturing precision

If conventional lithography is used to form patterns, then pattern uniformity is maintained, but further miniaturization becomes difficult

Engineering Contradiction:
Improvepattern uniformityVSAvoidpattern size
Core Design Contradiction:
Manufacturing precisionVSLength of moving object

Solution Approach 1:

The patent introduces a base pattern as an intermediary structure that mediates between conventional lithography capabilities and block copolymer self-assembly. The base pattern serves as a template that guides the self-assembly process, enabling the formation of miniaturized features that would be difficult to achieve with conventional lithography alone, while maintaining overall pattern uniformity through the structured guidance provided by the base pattern

Inventive Principle:
Principle #24Intermediary (Mediator)

3Length of moving object

If block copolymer directed self-assembly is used for pattern formation, then finer patterns are achieved, but etching resistance decreases

Engineering Contradiction:
Improvepattern sizeVSAvoidetching resistance
Core Design Contradiction:
Length of moving objectVSStrength

Solution Approach 1:

The patent creates a composite structure combining the base pattern material with the block copolymer material. This composite structure leverages the strengths of both materials - the base pattern provides structural support and etching resistance, while the block copolymer regions enable fine feature formation through self-assembly. The composite nature of the structure allows simultaneous achievement of miniaturization and maintained etching resistance

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the formation of miniaturized patterns with reduced roughness and improved Critical Dimension Uniformity (CDU), suitable for advanced microfabrication processes in semiconductor devices and other applications.

Implementation Method 1

The first polymer includes on at least one end of a main chain thereof a group capable of interacting with the base pattern

Methodology Applied
Scientific EffectInteraction between polymer and base pattern: Adsorption

Implementation Method 2

A surface of the coating is contacted with a highly polar solvent

Methodology Applied
Scientific EffectPhase separation induced by solvent contact: Phase Change

Implementation Method 3

The second polymer is capable of forming a phase separation structure through directed self-assembly

Methodology Applied
Scientific EffectDirected self-assembly: Self-Assembly

Implementation Method 4

Phase separation is permitted in the second composition to form phases after the filling of the second composition

Methodology Applied
Scientific EffectPhase separation: Phase Change

Data Source

PatentUS9847232B1Pattern-forming method
Publication Date: 2017.12.19 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US9847232B1 patent drawing
  • US9847232B1 patent drawing
  • US9847232B1 patent drawing

AI summary

A pattern-forming method includes forming a base pattern having recessed portions on a front face side of a substrate. A first composition is applied on lateral faces of the recessed portions of the base pattern, to form a coating. The first composition includes a first polymer which includes on at least one end of a main chain thereof a group capable of interacting with the base pattern. A surface of the coating is contacted with a highly polar solvent. The recessed portions are filled with a second composition. The second composition includes a second polymer which is capable of forming a phase separation structure through directed self-assembly. Phase separation is permitted in the second composition to form phases. A part of the phases is removed to form a miniaturized pattern. The substrate is etched directly or indirectly using the miniaturized pattern as a mask.