Patterned Substrate Drying Using Two-Layer Solid Fill Removal

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Solution Overview

Problem

Existing substrate drying processes often result in pattern collapse due to the removal of sublimable substances passing through the liquid phase, which can cause convex portions of the pattern to collapse.

Innovation Solution

A substrate processing method involving a two-layer laminate structure where a first material and a second material are applied in solid states to concave portions, and then removed through heating, light-emitting, or reaction processes using specific gases, preventing the need for a liquid phase and thus minimizing pattern collapse.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a sublimable substance solution is supplied to fill concave portions and then dried, then the concave portion can be filled with sublimable substance, but the pattern may collapse when the substance passes through liquid phase during drying

Engineering Contradiction:
Improvepattern integrityVSAvoidpattern collapse
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent applies sublimation phase transition to remove the first sublimable substance directly from solid to gas phase, avoiding the liquid phase that causes pattern collapse. For the second material, the patent uses decomposition or gas reaction to convert it directly to gas phase removal, also avoiding liquid phase. This phase transition strategy resolves the contradiction by eliminating the harmful liquid phase while maintaining effective material removal.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent changes the removal parameters by using different removal methods for different materials: heating for sublimation of the first material, and light-emitting or gas reaction for decomposition of the second material. These parameter changes enable direct solid-to-gas transitions without passing through liquid phase, preventing pattern collapse while achieving complete material removal.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a single sublimable substance is used to fill concave portions, then the process is simple, but it cannot reliably prevent pattern collapse in all cases

Engineering Contradiction:
Improvepattern collapse preventionVSAvoidmaterial layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses a composite two-layer structure: the first layer is a sublimable substance removed by heating, and the second layer is a decomposable material removed by light-emitting or gas reaction. This composite material approach improves reliability of pattern collapse prevention by using materials with different removal mechanisms, ensuring that neither material passes through the harmful liquid phase during removal.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent segments the filling material into two distinct layers with different properties and removal methods. The first sublimable substance layer is removed by heating, while the second decomposable material layer is removed by light-emitting or gas reaction. This segmentation allows each layer to be optimized for its specific removal mechanism, reliably preventing pattern collapse while managing the complexity through systematic division of functions.

Inventive Principle:
Principle #1Segmentation

3Loss of substance

If heating is applied to remove sublimable substance, then the substance can be sublimated and removed, but energy consumption increases

Engineering Contradiction:
Improvesublimable substance removalVSAvoidheating energy consumption
Core Design Contradiction:
Loss of substanceVSUse of energy by moving object

Solution Approach 1:

The patent employs periodic or selective heating actions: heating is applied specifically to the first sublimable substance layer at controlled temperatures, while the second decomposable material layer is removed using light-emitting or gas reaction without requiring high heating energy. This periodic and selective energy application achieves complete material removal while minimizing overall energy consumption compared to continuous high-temperature heating.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method reliably prevents pattern collapse by ensuring that the materials are removed in a solid state, maintaining the integrity of the substrate pattern during the drying process.

Implementation Method 1

removing the second material from the concave portion by performing at least one of a heating process, a light-emitting process, and a reaction process using a first gas with respect to the second material to sublimate, decompose, and gas-react the second material

Methodology Applied
Scientific EffectSublimation: Sublimation

Implementation Method 2

removing the second material from the concave portion by performing at least one of a heating process, a light-emitting process, and a reaction process using a first gas with respect to the second material to sublimate, decompose, and gas-react the second material

Methodology Applied
Scientific EffectPhotodecomposition: Photodissociation

Implementation Method 3

removing the first material from the concave portion by performing at least one of the heating process, the light-emitting process, and a reaction process using a second gas with respect to the first material to sublimate, decompose, and gas-react the first material

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS11935736B2Substrate processing method and substrate processing apparatus
Publication Date: 2024.03.19 TOKYO ELECTRON LTD
  • US11935736B2 patent drawing
  • US11935736B2 patent drawing
  • US11935736B2 patent drawing

AI summary

A substrate processing method for removing liquid on a substrate having an uneven pattern formed on a surface of the substrate and drying the substrate. The substrate processing method includes: forming a laminate having a two-layer structure including a first material in a solid state forming a lower layer and a second material in a solid state forming an upper layer, in a concave portion of the pattern; removing the second material from the concave portion by performing at least one of a heating process, a light-emitting process, and a reaction process using gas with respect to the second material to sublimate, decompose, and gas-react the second material; and removing the first material from the concave portion by performing at least one of the heating process, the light-emitting process, and the reaction process using gas with respect to the first material to sublimate, decompose, and gas-react the first material.