Polycrystalline Diamond Cutting Elements With High Compressive Stress

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Solution Overview

Problem

Cutting elements with diamond surfaces experience breakage and delamination due to residual compressive stress at the diamond layer-substrate interface, compromising wear resistance and service life during drilling operations.

Innovation Solution

The cutting elements feature a dome-shaped diamond surface with high compressive stress, engineered with a controlled ratio of cobalt crystal structures and potentially including transition layers, formed through high-pressure/high-temperature processing, to enhance wear resistance and minimize thermal expansion mismatch.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a diamond layer is formed on a carbide substrate through high-pressure/high-temperature sintering, then wear resistance is improved, but residual compressive stress causes breakage and delamination

Engineering Contradiction:
Improvewear resistanceVSAvoidresistance to breakage and delamination
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies parameter changes by modifying the cooling rate and temperature profile during HPHT processing. Specifically, it uses a controlled cooling rate of 5-50°C per minute and maintains the sintering temperature for 1-24 hours to optimize the diamond layer formation. This controlled parameter adjustment reduces thermal gradients and minimizes residual compressive stress while preserving wear resistance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transitions by controlling the crystallization of cobalt from liquid to solid phase during the cooling process. The specific cooling rate regime allows for controlled phase transformation that reduces internal stress. Additionally, the high-pressure/high-temperature process induces phase transition of carbon to diamond structure, creating a stress-managed diamond layer.

Inventive Principle:
Principle #36Phase transitions

2Duration of action of stationary object

If the diamond layer thickness is increased to improve wear resistance, then service life is extended, but residual stress and risk of delamination increase

Engineering Contradiction:
Improveservice lifeVSAvoidresistance to delamination
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent employs parameter changes by optimizing the thickness of the diamond layer to specific ranges (50-500 micrometers) and controlling the HPHT processing parameters including pressure (5-15 GPa), temperature (1300-2000°C), and cooling rate. This optimized parameter combination allows achieving sufficient wear resistance and service life while managing residual stress through controlled formation.

Inventive Principle:
Principle #35Parameter changes

3Stress or pressure

If the coefficient of thermal expansion mismatch between diamond layer and substrate is reduced, then residual stress is minimized, but material selection becomes more constrained

Engineering Contradiction:
Improveresidual compressive stressVSAvoidmaterial selection flexibility
Core Design Contradiction:
Stress or pressureVSAdaptability or versatility

Solution Approach 1:

The patent applies parameter changes by modifying the thermal processing parameters including heating rate (1-10°C per minute), holding temperature (1300-2000°C), and cooling rate (5-50°C per minute). These parameter adjustments allow the system to accommodate the inherent thermal expansion mismatch between diamond and carbide substrate, transforming the harmful stress into a manageable state that preserves both wear resistance and structural integrity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution increases wear resistance and resistance to crack formation, leading to improved operational service life and reduced breakage, with compressive stress levels exceeding 900 MPa and enhanced cobalt phase ratios contributing to these benefits.

Implementation Method 1

subjecting an assembly of diamond grains to high-pressure/high-temperature processing conditions to form the polycrystalline diamond

Methodology Applied
Scientific EffectPhase transition: Phase Change

Implementation Method 2

the high-pressure/high-temperature process used to sinter the diamond layer, form the PCD and attach the PCD layer to the underlying substrate

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 3

The diamond surface may have a high level compressive stress of greater than about 500 MPa, greater than about 900 MPa, greater than about 1,000 MPa, or in the range of from about 900 to 1,200 MPa

Methodology Applied
Scientific EffectCompressive stress: Compression

Data Source

PatentUS10100583B2Cutting elements with wear resistant diamond surface
Publication Date: 2018.10.16 SCHLUMBERGER TECH CORP
  • US10100583B2 patent drawing
  • US10100583B2 patent drawing
  • US10100583B2 patent drawing

AI summary

Cutting elements include polycrystalline diamond which may be attached to a substrate. The polycrystalline diamond may have a ratio of cubic to hexagonal cobalt crystalline structures of greater than about 1.2. The polycrystalline diamond may have a high level surface compressive stress of greater than about 500 MPa.