PCD Protective Element for Corrosion Resistance

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Solution Overview

Problem

Conventional polycrystalline diamond (PCD) constructions are susceptible to corrosion and erosion in aggressive environments, leading to delamination and reduced service life due to the degradation of solvent catalyst metals at the interface between the diamond bonded body and substrate.

Innovation Solution

Incorporating a protective element made from ultra-hard material, such as polycrystalline diamond, that extends along the substrate to cover the solvent metal catalyst rich zone, providing a barrier against corrosive and erosive attacks while maintaining the integrity of the attachment between the diamond bonded body and substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If solvent catalyst material is used to form conventional PCD, then diamond grain bonding is enhanced, but corrosion and erosion resistance deteriorates

Engineering Contradiction:
Improvediamond grain bondingVSAvoidcorrosion and erosion resistance
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The invention divides the PCD structure into distinct regions: a core region containing solvent catalyst material for bonding, and an outer protective region free of solvent catalyst material. This segmentation allows the bonding function and protection function to be separated spatially, resolving the contradiction between enhanced bonding and improved corrosion/erosion resistance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention applies different material compositions to different regions of the PCD structure. The core region has high solvent catalyst content for bonding, while the outer region has reduced or zero solvent catalyst content for protection. This local quality differentiation allows each region to optimize its specific function without compromising the other.

Inventive Principle:
Principle #3Local quality

2Strength

If solvent catalyst material is present in high concentration, then intercrystalline bonding is improved, but service life in corrosive environments deteriorates

Engineering Contradiction:
Improveintercrystalline bondingVSAvoidservice life
Core Design Contradiction:
StrengthVSDuration of action of stationary object

Solution Approach 1:

The PCD is segmented into a core region with high solvent catalyst concentration for bonding and an outer region with reduced solvent catalyst for durability. This spatial segmentation allows the structure to achieve both strong bonding and extended service life in corrosive environments.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The protective low-solvent region is formed during the HPHT process itself, before the PCD is exposed to corrosive environments. This preliminary creation of the protective barrier prevents corrosion from reaching the solvent catalyst-rich core region during service.

Inventive Principle:
Principle #10Preliminary action

3Strength

If HPHT processing is used to form PCD, then diamond grain bonding is enhanced, but susceptibility to delamination increases

Engineering Contradiction:
Improvediamond grain bondingVSAvoiddelamination resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention creates a layered structure where a protective outer region without solvent catalyst material shields the solvent catalyst-rich core region from environmental degradation. This segmentation prevents the delamination that would otherwise occur when solvent catalyst degrades in corrosive environments.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The protective outer region acts as an intermediary barrier between the solvent catalyst-rich core region and the corrosive environment. This intermediary layer prevents direct contact between the vulnerable solvent catalyst and corrosive agents, thereby preventing delamination.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The protective element effectively minimizes corrosion and erosion, ensuring a strong bond and extended service life of the PCD constructions by preventing material depletion and subsequent delamination.

Implementation Method 1

When subjected to the HPHT process, the solvent catalyst material within the substrate melts and infiltrates into the adjacent diamond grain volume to thereby catalyze the bonding together of the diamond grains

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

the solvent catalyst material within the substrate melts and infiltrates into the adjacent diamond grain volume

Methodology Applied
Scientific EffectInfiltration: Permeation

Implementation Method 3

Incorporating a protective element made from ultra-hard material, such as polycrystalline diamond, that extends along the substrate to cover the solvent metal catalyst rich zone, providing a barrier against corrosive and erosive attacks

Methodology Applied
Scientific EffectPhysical barrier protection: Physical Containment

Implementation Method 4

subjecting the diamond grains and solvent catalyst material to processing conditions of extremely high pressure/high temperature (HPHT)

Methodology Applied
Scientific EffectHigh pressure/high temperature processing: Pressure Increase

Implementation Method 5

the solvent catalyst material promotes desired intercrystalline diamond-to-diamond bonding between the grains, thereby forming a PCD structure

Methodology Applied
Scientific EffectIntercrystalline bonding: Chemical Bonding

Data Source

PatentUS10544627B2Polycrystalline diamond constructions with protective element
Publication Date: 2020.01.28 SMITH INTERNATIONAL INC
  • US10544627B2 patent drawing
  • US10544627B2 patent drawing
  • US10544627B2 patent drawing

AI summary

PCD constructions as disclosed comprise a ultra-hard body attached with a metallic substrate along a substrate extending between the body and the substrate. The construction includes a protective feature or element that is configured to protect a metal rich region or zone existing in the construction from unwanted effects of corrosion or erosion. The protective element extends from the body over the interface and along a portion of the substrate and may be integral with the.