Adsorption Filter with Phase Change Material Beads

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Solution Overview

Problem

Existing adsorption filters face challenges in enhancing heat-storing capacity and desorbing properties, particularly in the regeneration process, especially when dealing with fuel vapors in internal combustion engines.

Innovation Solution

The use of phase change materials, such as wax encapsulated in small beads with varying melting points distributed throughout the adsorption filter, combined with thermal conductivity fillers and a binder, to optimize heat storage and desorption efficiency by varying phase change temperatures along the filter's length and using different phase change materials in distinct areas for enhanced performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If phase change material is used in the form of small beads to rapidly absorb heat, then heat storage capacity is improved, but the beads may separate within the adsorption material

Engineering Contradiction:
Improveheat storage capacityVSAvoidseparation of phase change material beads
Core Design Contradiction:
Loss of energyVSStability of the object's composition

Solution Approach 1:

The phase change material beads are encapsulated within porous pellets that contain adsorption material. This nested structure allows the small beads (10 μm diameter) to be contained within larger pellets (1-3 mm diameter), preventing separation while maintaining rapid heat absorption capability. The porous structure of the pellets provides thermal conductivity pathways while holding the beads in place.

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The invention creates a composite structure where phase change material beads are combined with adsorption material (such as activated carbon) within porous pellets. This composite approach allows the small beads to function effectively for heat storage while being embedded in a matrix that prevents separation and maintains structural integrity during operation.

Inventive Principle:
Principle #40Composite materials

2Reliability

If phase change material with increasing melting points is used in the direction of flow, then adsorption effect is improved, but device complexity increases

Engineering Contradiction:
Improveadsorption effectVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention applies local quality by using phase change materials with different melting points in different regions of the filter. The entrance area contains materials with lower melting points (5-30°C) for immediate adsorption during filling, while the outlet end contains materials with higher melting points (60-70°C) for regeneration. This spatial variation optimizes performance at each location without requiring complex control systems.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The filter is segmented into different zones along the flow direction, each containing phase change materials with specific melting point ranges. This segmentation allows independent optimization of each zone for its specific function (adsorption vs. regeneration) while maintaining a relatively simple overall structure that can be manufactured as a layered composite.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration significantly increases the heat-storage capacity and improves desorption efficiency by maintaining favorable temperatures for adsorption and desorption processes, reducing temperature fluctuations and pressure drops, while preventing separation of small phase change material beads.

Implementation Method 1

Wax melts when heat is applied. In doing so, the wax utilizes the heat supplied to it to break the bonds of its molecules instead of raising its temperature. Instead of storing heat, liquefied wax stores energy of bonding, which is then released again as heat on solidification, i.e., with a phase change from liquid to solid.

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

the wax utilizes the heat supplied to it to break the bonds of its molecules instead of raising its temperature. Instead of storing heat, liquefied wax stores energy of bonding, which is then released again as heat on solidification

Methodology Applied
Scientific EffectLatent heat: Latent Heat

Implementation Method 3

adsorption filter for fuel vapors

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

combined with thermal conductivity fillers

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS7604691B2Adsorption filter for fuel vapors
Publication Date: 2009.10.20 MAHLE FILTERSYSTEME GMBH
  • US7604691B2 patent drawing
  • US7604691B2 patent drawing

AI summary

The invention relates to an adsorption filter for fuel vapors, particularly from the fuel tank of a combustion engine of a motor vehicle, which can be regenerated by desorptive reverse flow back flushing and which interacts with heat accumulating substances via the adsorbable or desorbable filter material. The aim of the invention is to increase the heat accumulability inside the filter material. To this end, the heat accumulating substances consist of phase-change materials (PCM) that are distributed in small units within the reactive filter material.