PCM Capsule with Graphite Core and Polypropylene Skin

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Solution Overview

Problem

Existing heat exchange systems in heating systems have limited heat capacity due to the use of conventional heat exchange fluids like water, and previous attempts to enhance this with phase change materials (PCMs) have been hindered by the presence of solvents in the core materials, which inhibit the desired heat storage and phase transition behaviors.

Innovation Solution

A capsule design featuring a core of phase change material, such as salt hydrate, with added graphite for cohesion and heat transfer enhancement, encapsulated in a thin, watertight skin of polypropylene, allowing for improved heat storage and transfer without solvent interference, and arranged in a buffer system to increase heat capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If phase change material is used in the core to enhance heat capacity, then heat storage ability is improved, but solvent interference deteriorates phase transition behavior

Engineering Contradiction:
Improveheat storage abilityVSAvoidphase transition behavior
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent removes the solvent from the core material composition entirely. The core consists solely of phase change material particles (3-5mm diameter) bound together through compression without any solvent medium, thereby eliminating solvent interference with phase transitions while maintaining heat storage capacity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent creates a composite structure where phase change material particles are bound together through mechanical compression to form a cohesive core. This composite approach allows the PCM particles to maintain their phase transition properties while forming a stable, handleable core structure

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If loose core material is used to allow phase change, then heat transfer is improved, but form retention deteriorates handling ease

Engineering Contradiction:
Improveheat transferVSAvoidhandling ease
Core Design Contradiction:
Use of energy by moving objectVSEase of operation

Solution Approach 1:

The core material is pre-compressed into a stable, handleable form (spheres, cubes, or irregular shapes) before encapsulation. This preliminary form-giving action maintains the loose particle structure necessary for heat transfer while providing sufficient mechanical stability for handling and processing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

A thin skin (10-600μm thickness) is applied around the compressed core to provide containment and structural integrity. The skin is thin enough to allow heat transfer while providing sufficient mechanical strength for handling the core material

Inventive Principle:
Principle #30Flexible shells and thin films

3Use of energy by moving object

If thin skin is used to reduce interference, then heat transfer efficiency is improved, but watertightness deteriorates protection ability

Engineering Contradiction:
Improveheat transfer efficiencyVSAvoidwatertightness
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The skin thickness is optimized to a specific range (10-600μm) that balances heat transfer efficiency with watertight protection. The skin material is selected from thermoplastics with appropriate thermal and barrier properties to achieve both requirements simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The capsule structure forms a composite system where the thin thermoplastic skin encapsulates the PCM core, creating a unified structure that provides both thermal efficiency and fluid protection through the synergistic combination of thin-walled containment and phase change material

Inventive Principle:
Principle #40Composite materials

4Reliability

If multi-part skin structure is used to ensure watertightness, then protection ability is improved, but manufacturing complexity increases

Engineering Contradiction:
ImprovewatertightnessVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The skin is applied as a single continuous piece around the core through injection molding, eliminating seams and joints that would require multiple parts. This one-piece construction achieves watertightness while simplifying the manufacturing process to a single molding operation

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The capsule design significantly enhances the heat capacity of the buffer system by preventing solvent contact with the phase change material, ensuring long-term watertight properties and efficient heat transfer, while allowing for easier handling and integration into existing heat exchange systems.

Implementation Method 1

a core (15) of phase change material

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

phase change materials could be employed to enhance the heat capacity of a buffer

Methodology Applied
Scientific EffectLatent heat: Latent Heat

Implementation Method 3

the core comprises graphite. Addition of graphite to the phase change material will enhance cohesion of the phase change material and heat storage and heat transfer through the phase change material

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 4

The watertight skin prevents the phase change material from coming into contact with the heat exchange fluid

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Data Source

PatentEP2914376B1Capsule comprising phase change material, assembly of capsules and method of forming the capsule
Publication Date: 2017.03.01 FLAMCO BV
  • EP2914376B1 patent drawing
  • EP2914376B1 patent drawing
  • EP2914376B1 patent drawing

AI summary

The present invention relates to a core of a capsule, capsules having the cores comprising phase changing material (PCM) to be processed to be form retaining in particular during subsequent steps of applying a skin to form the capsule, as well as an assembly of a plurality of such capsules, use thereof in a buffer, and a production method for manufacturing such capsules or assemblies, for instance in strings.