Elastomeric Seal with Phase Change Material for Cold Resilience

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Solution Overview

Problem

Elastomeric seals in high-pressure retaining systems and harsh weather conditions face damage from rapid temperature changes, becoming brittle and losing sealability at low temperatures, while materials resistant to low temperatures lack high-temperature stability and chemical inertness.

Innovation Solution

A polymer seal element comprising an elastomeric composite blended with a phase-changing material (PCM) that releases heat upon cooling, maintaining sealability and resilience by maintaining the elastomeric polymer above its glass transition temperature, even in cold environments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If elastomeric seals with high glass transition points are used for high temperature stability and chemical resistance, then high-temperature stability and chemical inertness are improved, but low-temperature behavior deteriorates and the seal becomes brittle

Engineering Contradiction:
Improvehigh-temperature stability and chemical resistanceVSAvoidlow-temperature brittleness
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention uses a composite material consisting of an elastomeric polymer blended with a phase change material (PCM). The elastomeric polymer provides high-temperature stability and chemical resistance, while the PCM prevents low-temperature brittleness by undergoing phase transformation and releasing heat to maintain the seal above its glass transition temperature.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention utilizes the phase transition properties of the PCM, which transforms at a specific temperature range. During this phase change, the PCM releases latent heat that prevents the elastomeric polymer from cooling below its glass transition point, thereby maintaining flexibility and preventing brittleness in cold conditions.

Inventive Principle:
Principle #36Phase transitions

2Strength

If elastomers with very low glass transition points are used to tolerate low temperatures, then low-temperature flexibility is improved, but chemical resistance deteriorates

Engineering Contradiction:
Improvelow-temperature flexibilityVSAvoidchemical resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention creates a composite where the elastomeric polymer matrix provides chemical resistance while the embedded PCM provides low-temperature flexibility. This allows the seal to maintain both chemical inertness and cold-weather performance without compromising either property.

Inventive Principle:
Principle #40Composite materials

3Stress or pressure

If rapid depressurization occurs causing Joule-Thomson cooling, then pressure reduction is achieved, but temperature drop causes the seal to become brittle and crack

Engineering Contradiction:
Improvepressure reductionVSAvoidseal integrity
Core Design Contradiction:
Stress or pressureVSReliability

Solution Approach 1:

The PCM undergoes phase transformation at a temperature range that includes the expected minimum temperature during rapid depressurization. This phase change releases latent heat that counteracts the Joule-Thomson cooling effect, preventing the seal from reaching its glass transition temperature and maintaining seal integrity during pressure reduction events.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The invention converts the harmful rapid cooling effect of Joule-Thomson expansion into a beneficial trigger for PCM phase change. The temperature drop that would normally cause brittleness instead activates the PCM's heat release mechanism, which then prevents the seal from becoming brittle.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The PCM embedded in the elastomeric composite delays cooling, prevents fluid leakage, and enhances the seal's resilience and reliability by providing thermal energy during temperature drops, ensuring effective sealing in transient cold conditions.

Implementation Method 1

a phase changing material (PCM) that releases heat upon cooling

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

the PCM has a heat of fusion larger than 100 kJ/kg, a phase transition point within the temperature range of 233-288 K and is able to provide heat to the elastomeric polymer upon cooling

Methodology Applied
Scientific EffectLatent heat: Latent Heat

Implementation Method 3

the inherently low thermal conductivity of polymers, can withstand a time period of exposure to cold environment while maintaining its sealing capability

Methodology Applied
Scientific EffectThermal energy storage: Thermal Energy Storage

Data Source

PatentEP2999763B1Seal element
Publication Date: 2018.10.31 FMC KONGSBERG SUBSEA AS
  • EP2999763B1 patent drawingFigure 1
  • EP2999763B1 patent drawing
  • EP2999763B1 patent drawing

AI summary

The present invention provides a seal element made in an elastomeric composite, said material comprising an elastomeric polymer and a phase change material (PCM), wherein the PCM is able to provide thermal energy to the elastomeric polymer upon cooling to the phase transition point of the PCM.