Pearlescent Container Using Immiscible Siloxane Fluid

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Solution Overview

Problem

Existing pearlescent containers made from thermoplastic materials face issues such as reduced surface smoothness, unwanted weld and flow lines, and compromised recyclability due to the use of particles like mica and glass fibers, and processing difficulties with thermoplastic material combinations.

Innovation Solution

A pearlescent container is created using a thermoplastic material with a Total Luminous Transmittance value of at least 80% and a siloxane fluid with a viscosity of no greater than 1,000,000 cst, forming an immiscible lamellar structure with a Refractive Index difference of at least 0.1, which is blow molded to achieve a pearlescent appearance without the drawbacks of prior methods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If particles such as mica, aluminum oxide, silicon dioxide, or glass fibers are mixed with thermoplastic materials to achieve a pearlescent appearance, then the container surface exhibits a desirable pearlescent effect, but the surface smoothness deteriorates and unwanted weld lines and flow lines appear

Engineering Contradiction:
Improvepearlescent appearanceVSAvoidsurface smoothness
Core Design Contradiction:
Illumination intensityVSManufacturing precision

Solution Approach 1:

The invention changes the physical state of the siloxane from solid particles to fluid form, and controls its viscosity parameter (no greater than 1,000,000 cst) to enable it to flow and distribute uniformly during processing, eliminating surface defects while maintaining pearlescent appearance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite material system consisting of thermoplastic material and siloxane fluid that are immiscible but form a stable dispersion. The refractive index difference (at least 0.1) between the two components generates the pearlescent effect without the need for solid particles

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If particles such as mica, aluminum oxide, silicon dioxide, or glass fibers are incorporated into thermoplastic materials to create a pearlescent container, then the container surface achieves a pearl-like appearance, but the container strength deteriorates due to weld lines and flow lines

Engineering Contradiction:
Improvepearlescent appearanceVSAvoidcontainer strength
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

The invention changes the siloxane from solid particle form to fluid form with controlled viscosity, allowing it to be uniformly distributed in the melt without creating weak points. The fluid siloxane does not interfere with the welding of melt fronts, thereby maintaining container strength

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention extracts the harmful solid particle component from the system and replaces it with siloxane fluid, which provides the desired optical effect without compromising the mechanical integrity and weldability of the thermoplastic material

Inventive Principle:
Principle #2Taking out (Extraction)

3Illumination intensity

If combinations of thermoplastic materials are used to provide a pearl gray or pearl-like appearance, then the container achieves a pearlescent effect, but processing difficulties arise due to un-matching melting points requiring compatibilizers

Engineering Contradiction:
Improvepearlescent appearanceVSAvoidprocessing ease
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The invention changes the approach from using multiple thermoplastic materials with different melting points to using a single thermoplastic material combined with siloxane fluid. This simplifies the processing conditions and eliminates the need for compatibilizers while maintaining the pearlescent appearance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The siloxane fluid acts as an intermediary that provides the pearlescent effect without requiring complex multi-material blends. It disperses uniformly in the thermoplastic melt and does not interfere with the processing of the base thermoplastic material

Inventive Principle:
Principle #24Intermediary (Mediator)

4Illumination intensity

If chemically active thermoplastic materials such as methacrylic are used in combinations to achieve a pearlescent appearance, then the container exhibits desired aesthetic properties, but the container stability deteriorates

Engineering Contradiction:
Improvepearlescent appearanceVSAvoidcontainer stability
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The invention extracts the chemically active components from the material combination and replaces them with siloxane fluid, which is chemically inert. This eliminates stability issues while maintaining the pearlescent appearance through the refractive index difference between the siloxane and thermoplastic material

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in a container with improved glossiness, reduced weld and flow lines, and enhanced surface smoothness, while maintaining recyclability and aesthetic appeal, through the formation of a lamellar structure that produces a light interference effect, similar to natural pearls.

Implementation Method 1

The pearlescent effect of the container surface disclosed herein is achieved by the light interference effect on such particles

Methodology Applied
Scientific EffectLight interference: Interference

Implementation Method 2

have a Refractive Index difference of at least about 0.1

Methodology Applied
Scientific EffectRefraction: Refraction

Data Source

PatentUS9676135B2Pearlescent container
Publication Date: 2017.06.13 PROCTER & GAMBLE CO
  • US9676135B2 patent drawing
  • US9676135B2 patent drawing

AI summary

A pearlescent container comprising about 86% to about 99.99% of a thermoplastic material having a Total Luminous Transmittance value of at least about 80%, about 0.01% to about 5% of a siloxane fluid having a viscosity of no greater than about 1,000,000 cst, wherein said thermoplastic material and said siloxane fluid are immiscible, forms a lamellar structure, and have a Refractive Index difference of at least about 0.1.