Alkali-Soluble PECVD Coating for Reusable PET Bottle Washing

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for cleaning and coating reusable PET bottles using sodium hydroxide solution cause premature wear and tear, surface roughness, shrinkage, and contamination issues, leading to reduced lifespan and inability to switch between flavored and unflavored beverages due to flavor migration.

Innovation Solution

A protective layer formed from HMDSO, HMDSN, or HMDS is applied using PECVD, which is soluble in alkaline baths, preventing surface attack and allowing for easy removal of biofilms and contaminants, combined with adhesion and barrier layers to enhance protection and reduce material usage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If plastic containers are disposed of after single use, then hygiene is maintained and contamination is prevented, but environmental pollution increases and resource waste occurs

Engineering Contradiction:
ImprovehygieneVSAvoidenvironmental pollution
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent implements a system where single-use plastic containers are collected, automatically washed and disinfected in industrial washing machines, then reused multiple times. This recovery process eliminates environmental pollution from disposal while maintaining hygiene through automated cleaning cycles that reach temperatures of 70-90°C and use food-safe detergents and disinfectants.

Inventive Principle:
Principle #34Discarding and recovering

Solution Approach 2:

The containers are equipped with self-identifying features such as RFID tags, data matrices, or color codes that enable automatic recognition by washing machines. This allows the containers to effectively 'identify themselves' for appropriate cleaning protocols, enabling high-speed automated processing without manual intervention while maintaining consistent hygiene standards across thousands of containers.

Inventive Principle:
Principle #25Self-service

2Loss of substance

If plastic containers are reused without proper cleaning, then resource waste is reduced, but bacterial growth and contamination occur

Engineering Contradiction:
Improveresource wasteVSAvoidbacterial growth
Core Design Contradiction:
Loss of substanceVSObject-generated harmful factors

Solution Approach 1:

The washing machine system employs strong oxidizing agents including ozone, peracetic acid, and hydrogen peroxide to eliminate bacteria and organic contaminants from containers. These oxidants effectively sanitize surfaces at lower temperatures than traditional thermal methods, ensuring thorough disinfection while reducing energy consumption and protecting container material integrity during repeated washing cycles.

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Solution Approach 2:

The system applies protective coatings to container surfaces before reuse, creating a barrier that prevents bacterial adhesion and makes subsequent cleaning more effective. These coatings are applied during the washing process and provide ongoing protection against contamination between wash cycles, ensuring hygiene is maintained throughout the container's reuse lifecycle.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Productivity

If industrial washing machines process containers at high speed, then productivity increases, but thorough cleaning and disinfection may be compromised

Engineering Contradiction:
Improvewashing speedVSAvoidcleaning thoroughness
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The washing process is divided into multiple sequential stages including pre-rinsing, main washing with detergents, rinsing, and disinfection with oxidants. Each stage targets specific types of contamination and uses optimized parameters for that phase. This segmentation allows thorough cleaning to be achieved through cumulative effect of multiple brief treatments rather than requiring prolonged single-stage processing, maintaining both speed and effectiveness.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Food-safe detergents and disinfectants serve as intermediary substances that enhance the cleaning and disinfection effectiveness during brief contact periods. These chemical intermediaries actively break down and remove contaminants, allowing thorough sanitation to be achieved in seconds rather than minutes, thus enabling high-speed processing without compromising cleaning quality.

Inventive Principle:
Principle #24Intermediary (Mediator)

Data Source

PatentEP4247722B1Process for washing reusable plastic container, process for coating containers of this type, and container treatment machine for the beverage industry
Publication Date: 2026.05.20 KHS GMBH
  • EP4247722B1 patent drawing
  • EP4247722B1 patent drawing
  • EP4247722B1 patent drawing

AI summary

The invention relates to a reusable plastic container, more particularly a PET bottle, comprising a main body and a protective layer deposited on the main body, the protective layer at least partly covering the main body and being made of a material soluble in an alkaline bath. The invention also relates to a process for washing reusable plastic containers of this type, wherein the protective layer is completely washed off during the washing in an alkaline bath of a container-washing machine. Furthermore, the invention also relates to a process for coating containers, wherein: - the protective layer is deposited on the inner surface of the main body of the container by means of a PECVD process for microwave-induced plasma reaction; - HMDSO, HMDSN or HMDS or a mixture of at least two of these gases is used as a process gas and argon, oxygen, helium or nitrogen is used as a carrier gas; - the microwave pulse power P_Puls is controlled in accordance with the duty cycle t_on / (t_on + t_off), and the relation for the average microwave power P_mittel is: P_mittel = P_Puls x t_on / (t_on + t_off), where t_on is the pulse duration and t_off is the pause time. In addition, the invention also relates to a container treatment machine for the beverage industry, more particularly a cleaning machine or a coating machine, comprising a microprocessor, a programmable computer or an electronic circuit, in which one of the processes according to the invention is carried out.