Peel-off Patterning for Organic Optoelectronic Devices

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Solution Overview

Problem

Current methods for fabricating organic photovoltaic (OPV) modules face challenges in achieving high geometric fill factor (GFF) and efficient large-scale production due to issues with interconnection widths and the use of chemically sensitive materials.

Innovation Solution

A method involving photolithographic patterning with a polymer patterning layer, allowing for the creation of patterned organic layers with precise control over interconnection widths, thereby achieving high GFF and minimizing damage to chemically sensitive materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional photolithographic patterning is used to create narrow interconnections, then geometric fill factor is improved, but chemically sensitive organic materials are damaged by chemical etchants

Engineering Contradiction:
Improvegeometric fill factorVSAvoiddamage to organic materials
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

A polymer lift-off layer is introduced as an intermediary between the metal interconnection layer and the underlying organic materials. This polymer layer is patterned using photolithography and then removed by mechanical peeling, allowing the metal to be deposited and patterned without exposing the organic materials to chemical etchants. The polymer acts as a sacrificial mediator that protects the chemically sensitive organic layers while enabling precise patterning.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If mechanical scribing is used for patterning, then chemical sensitivity is avoided, but interconnection widths are too large to achieve high GFF

Engineering Contradiction:
Improvechemical damage to materialsVSAvoidinterconnection width
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The polymer lift-off layer serves as a mediator that enables the use of photolithographic patterning (which achieves narrow interconnection widths) while avoiding the need for chemical etching. The metal is deposited over the patterned polymer, and the polymer is then mechanically peeled away, taking the metal pattern with it. This combines the precision of photolithography with the mechanical removal approach that avoids chemical damage.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If laser ablation is used for patterning, then processing speed is improved, but control over interconnection widths and GFF is reduced

Engineering Contradiction:
Improvefabrication speedVSAvoidinterconnection width control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The polymer lift-off layer is patterned in advance using photolithography before metal deposition. This preliminary patterning step establishes precise interconnection width definitions through standard photolithographic techniques, allowing subsequent metal deposition and lift-off to proceed with controlled dimensions. The pre-patterned polymer guide the entire subsequent fabrication process.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables the fabrication of OPV modules with a GFF of greater than 90%, reducing manufacturing imperfections and maintaining high efficiency, even at large scales.

Implementation Method 1

A method involving photolithographic patterning with a polymer patterning layer

Methodology Applied
Scientific EffectPhotolithography: Photopolymerisation

Data Source

PatentUS12207535B2Peel-off patterning method for fabrication of organic optoelectronic devices
Publication Date: 2025.01.21 THE RGT UNIV OF MICHIGAN
  • US12207535B2 patent drawing
  • US12207535B2 patent drawing
  • US12207535B2 patent drawing

AI summary

A method of fabricating an organic optoelectronic device comprises positioning a patterning layer over a substrate, etching the patterning layer using a photolithographic process to create an etched patterning layer, positioning a layer of an organic material over the etched patterning layer, and removing at least a portion of the etched patterning layer and at least a portion of the layer of the organic material to create a patterned organic layer over the substrate.