Pre-activation of Polymer Electrolyte Fuel Cell Stacks

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Solution Overview

Problem

The activation of polymer electrolyte fuel cell stacks is time-consuming and energy-intensive, requiring hours or days, which restricts mass production and increases costs due to the need for extensive hydrogen use, equipment, and labor, and also poses challenges in detecting physical damage to the membrane electrode assembly during assembly.

Innovation Solution

An apparatus that pre-activates the fuel cell by supplying water vapor while hot pressing a unit cell stack with gas diffusion layers on both sides of a membrane electrode assembly, allowing for simultaneous arrangement, fixation, and activation, as well as monitoring for physical damage through vacuum degree changes, thereby reducing activation time and energy consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If activation is performed after assembling the fuel cell stack, then the fuel cell achieves proper operation, but the process requires hours or days of time consumption

Engineering Contradiction:
Improvefuel cell operationVSAvoidactivation time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent applies preliminary action by performing the activation process before assembling the fuel cell stack. The method involves placing the membrane electrode assembly between gas diffusion layers, applying heat and pressure to hot-press them together, and simultaneously supplying water vapor to activate the catalyst layers. This pre-activation eliminates the need for lengthy post-assembly activation, reducing the process from hours or days to merely the hot-pressing duration while ensuring proper fuel cell operation.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If conventional activation is performed, then the fuel cell becomes operational, but extensive hydrogen use, equipment, and labor are required increasing costs

Engineering Contradiction:
Improvefuel cell operationVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent performs activation beforehand during the hot-pressing stage, eliminating the need for separate activation equipment and extensive hydrogen consumption. The water vapor supplied during hot-pressing suffices to activate the catalyst layers, significantly reducing material consumption, equipment requirements, and labor costs compared to conventional post-assembly activation methods.

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If the membrane electrode assembly is assembled first, then the fuel cell structure is complete, but physical damage cannot be detected until activation

Engineering Contradiction:
Improveassembly completionVSAvoidphysical damage detection
Core Design Contradiction:
Ease of manufactureVSDifficulty of detecting and measuring

Solution Approach 1:

The patent incorporates feedback by monitoring the hot-pressing process parameters (temperature, pressure, time) and the water vapor supply during pre-activation. Any abnormalities in these parameters can indicate physical damage to the membrane electrode assembly, allowing detection before final assembly. This real-time monitoring provides immediate feedback on the condition of the components during the pre-activation stage.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces the time and energy required for fuel cell stack activation, enhances productivity, and allows for early detection of membrane electrode assembly damage, thereby minimizing production costs and improving stack performance.

Implementation Method 1

a polymer electrolyte membrane 10 capable of conducting protons

Methodology Applied
Scientific EffectProton conduction: Conduction (electrical)

Implementation Method 2

electrode catalyst layers applied on both sides of the polymer electrolyte membrane 10 to allow reaction of oxygen and hydrogen

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Implementation Method 3

hot pressing a unit cell stack with gas diffusion layers stacked on both sides of a membrane electrode assembly

Methodology Applied
Scientific EffectHot pressing: Heating

Implementation Method 4

hydrating the polymer electrolyte membrane and electrolytes included in the electrodes to increase mobility of protons

Methodology Applied
Scientific EffectHydration: Absorption (physical)

Implementation Method 5

monitoring for physical damage through vacuum degree changes

Methodology Applied
Scientific EffectVacuum measurement: Vacuum

Data Source

PatentUS8685590B2System for pre-activation of polymer electrolyte fuel cell (PEFC)
Publication Date: 2014.04.01 KOREA INST OF ENERGY RES
  • US8685590B2 patent drawing
  • US8685590B2 patent drawing
  • US8685590B2 patent drawing

AI summary

An apparatus for pre-activation of a polymer electrolyte fuel cell includes a first plate and a second plate hot pressing the unit cell stack, each having a flow channel supplying water vapor to opposing inner surfaces with the unit cell stack therebetween and including a resistor producing heat, a compressor, a temperature controller and a water vapor supplier connected to the flow channels of the plates. The apparatus for pre-activating a polymer electrolyte fuel cell may be used to prepare a prep-activated integrated body of a polymer electrolyte fuel cell membrane electrode assembly and gas diffusion layers by performing hot pressing while supplying water vapor to the unit cell stack to hydrate the polymer electrolyte membrane. And the apparatus for pre-activating a polymer electrolyte fuel cell is used to monitor physical damage of the membrane electrode assembly based on the change of degree of vacuum at a fuel electrode side and an air electrode side using, thereby detecting the leaking membrane electrode assembly in advance.