PEG-Free Low Viscosity Oil-in-Water Emulsion

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Solution Overview

Problem

Existing low viscosity oil-in-water emulsions require high amounts of emulsifiers for stability, making them commercially unviable for high oil concentrations and posing safety concerns due to the use of ethoxylated emulsifiers, which are also less preferred in natural cosmetics.

Innovation Solution

A stable low viscosity oil-in-water emulsion is achieved using a combination of PEG-free primary emulsifiers such as alkyl polyglucosides and long chained polyglycerol esters, along with a secondary emulsifier like short chained polyglycerol esters or sorbitan esters, at specific ratios, which reduces the overall emulsifier-to-oil ratio and eliminates the need for ethoxylated components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high amounts of ethoxylated emulsifiers are used to achieve stability in low viscosity oil-in-water emulsions, then the emulsion stability is improved, but the safety concerns and manufacturing complexity increase due to the hazardous nature of ethylene oxide

Engineering Contradiction:
Improveemulsion stabilityVSAvoidsafety concerns from ethylene oxide
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent removes ethoxylated emulsifiers (derived from hazardous ethylene oxide) from the formulation and replaces them with alternative emulsifying agents that provide comparable or superior stability without the associated safety risks and manufacturing complexities

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical composition parameters by substituting ethoxylated emulsifiers with non-ethoxylated alternatives, fundamentally altering the formulation approach while maintaining emulsion stability through different emulsifying mechanisms

Inventive Principle:
Principle #35Parameter changes

2Reliability

If ethoxylated emulsifiers are used in cosmetic emulsions, then emulsion stability is achieved, but the natural ingredient preference and market acceptance decrease

Engineering Contradiction:
Improveemulsion stabilityVSAvoidcompatibility with natural ingredient preference
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent extracts and eliminates ethoxylated emulsifiers from the formulation, replacing them with emulsifying agents that align with consumer preference for natural ingredients while maintaining the required emulsion stability

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention employs composite emulsifying systems combining multiple non-ethoxylated emulsifiers that work synergistically to achieve stability comparable to ethoxylated systems, while meeting natural ingredient preferences

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If the emulsifier-to-oil ratio is reduced to lower costs and improve commercial viability, then manufacturing cost decreases, but emulsion stability deteriorates

Engineering Contradiction:
Improvecommercial viabilityVSAvoidemulsion stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent optimizes the emulsifier-to-oil ratio parameters and adjusts emulsifier selection to achieve effective stabilization at lower emulsifier concentrations, improving commercial viability while maintaining stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite emulsifying systems where multiple emulsifiers work synergistically to provide adequate stability at reduced total emulsifier levels, making the formulation more commercially viable

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The emulsion maintains stability and low viscosity, allowing for effective use in cosmetic applications with improved sprayability and reduced emulsifier content, suitable for high oil concentrations without phase separation or significant viscosity changes during storage or use.

Implementation Method 1

a stable low viscosity oil-in-water emulsion

Methodology Applied
Scientific EffectEmulsion: Emulsion

Implementation Method 2

a primary emulsifier selected from A1) alkyl polyglucosides... A2) long chained polyglycerol esters

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 3

a secondary emulsifier selected from B1) short chained polyglycerol esters... B2) short chained sorbitan esters

Methodology Applied
Scientific EffectEmulsion: Emulsion

Data Source

PatentUS10292925B2Peg free stable low viscosity oil-in-water emulsion and use thereof
Publication Date: 2019.05.21 EVONIK OPERATIONS GMBH
  • US10292925B2 patent drawing
  • US10292925B2 patent drawing

AI summary

The present invention relates to a PEG free, stable, low viscosity classic oil-in-water emulsion and the use and preparation thereof. The oil-in-water emulsion comprises, A) a primary emulsifier selected from alkyl polyglucosides and long chained polyglycerol esters, B) a secondary emulsifier selected from short chained polyglycerol esters and short chained sorbitan esters, and optionally a thickener if the amount of secondary emulsifier is below 2.5 wt. %. The emulsion is a classic emulsion and can be sprayable. The emulsion is suitable to prepare spray or foam emulsion products with good application effect.