Pellicle Agglutinant Layer Bubble Suppression

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Solution Overview

Problem

In photolithography, the densification of patterns and shorter wavelengths of exposure light require a pellicle agglutinant layer with high reliability and uniformity, but existing methods struggle with air bubble contamination, leading to inadequate adhesion and deformation issues, and increasing manufacturing costs.

Innovation Solution

The agglutinant structure is procured using an adhesive prepared under a helium gas atmosphere, which suppresses air bubble contamination through steps like storing, pressurizing, stirring, and de-foaming, ensuring a bubble-free layer for the pellicle.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a coating layer of silicone resin is formed over the pellicle frame surface to prevent air bubbles, then air bubble contamination is reduced, but manufacturing cost increases

Engineering Contradiction:
Improveair bubble contaminationVSAvoidmanufacturing cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent applies the inert atmosphere principle by conducting the agglutinant preparation process in a nitrogen gas environment. This prevents air (oxygen) from dissolving into the agglutinant during mixing and storage, thereby eliminating air bubble contamination without requiring additional coating layers or increasing manufacturing complexity

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The patent implements preliminary action by preparing the agglutinant in advance under a nitrogen atmosphere and storing it in nitrogen-filled containers before application. This pre-preparation in an inert environment ensures that no air bubbles are introduced during subsequent handling or application processes

Inventive Principle:
Principle #10Preliminary action

2Reliability

If the agglutinant layer is required to have higher uniformity and no air bubbles, then adhesion reliability improves, but manufacturing complexity increases

Engineering Contradiction:
Improveadhesion reliabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses a nitrogen atmosphere throughout the agglutinant preparation process, from mixing to storage to application. This consistent inert environment prevents air bubble formation and ensures uniform quality without requiring complex additional equipment or processes

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The patent introduces nitrogen gas as an intermediary medium to replace air during the agglutinant preparation process. This intermediary atmosphere acts as a barrier between the agglutinant and atmospheric air, preventing oxygen dissolution and air bubble formation while simplifying the overall manufacturing approach

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If air bubbles are excluded from the agglutinant layer through stringent quality control, then pellicle quality improves, but production yield decreases

Engineering Contradiction:
Improvepellicle qualityVSAvoidproduction yield
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent implements a nitrogen atmosphere system that covers the entire agglutinant preparation and application process. This prevents air bubble contamination at the source, ensuring high pellicle quality without requiring post-manufacturing inspection and rejection of defective items, thereby maintaining high production yield

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively reduces air bubble contamination in the agglutinant layer, maintaining low manufacturing costs and ensuring high-quality, reliable pellicles suitable for semiconductor devices with minimal distortion.

Implementation Method 1

pressurizing, stirring, and de-foaming

Methodology Applied
Scientific EffectPressurization: Pressurisation

Implementation Method 2

de-foaming, ensuring a bubble-free layer

Methodology Applied
Scientific EffectDe-foaming: Cavitation

Data Source

PatentUS10712658B2Method of procuring an agglutinant structure and a method of manufacturing a pellicle including said agglutinant procuring method
Publication Date: 2020.07.14 SHIN ETSU CHEMICAL CO LTD
  • US10712658B2 patent drawing
  • US10712658B2 patent drawing
  • US10712658B2 patent drawing

AI summary

There is provided a method for procuring an agglutinant structure or in particular an agglutinant layer, from an agglutinant material, which is laid on an end face of a pellicle frame for gluing the pellicle to a photomask, wherein the agglutinant material is processed into the agglutinant layer passing through one more stages wherein the material is under a helium gas atmosphere; the invention is also about a manufacturing method of a pellicle wherein the agglutinant layer is procured in the above described manner.