Peptide-Based Vulcanization Accelerator for Rubber

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Solution Overview

Problem

Current vulcanization processes using guanidines in rubber compositions face challenges such as toxicity, premature vulcanization, and migration issues, leading to undesirable mixing and rigidity problems in tire production, while existing alternatives like quaternary ammonium salts and dithiophosphates have safety concerns and inefficiencies in scorch time and crosslinking.

Innovation Solution

A vulcanizable elastomeric composition using a secondary accelerator compound with a specific chemical structure, such as 2-amino-1,3-propanediol or its derivatives, which promotes quick vulcanization without short scorch times and effectively disperses silica, reducing the Payne effect and migration, and is derived from natural sources with harmless reagents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If guanidines are used as secondary accelerators in vulcanization, then vulcanization speed is improved, but toxicity and migration issues occur leading to premature vulcanization and rigidity problems

Engineering Contradiction:
Improvevulcanization speedVSAvoidtoxicity and migration
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces traditional guanidine accelerators with a biodegradable peptide-based accelerator that decomposes into harmless amino acids and ammonia after fulfilling its vulcanization function. This disposable approach eliminates long-term toxicity and migration issues while maintaining high vulcanization speed, as the accelerator is designed to be consumed and degraded after use.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent converts the potentially harmful decomposition products of the accelerator into beneficial components. The peptide accelerator decomposes into amino acids that can actually benefit the rubber matrix, and ammonia that can serve as a natural blowing agent or be neutralized. This transforms what would normally be harmful waste products into useful or harmless substances.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Productivity

If dithiocarbamates are used as accelerators, then crosslinking speed is improved, but scorch time becomes too short causing processability problems

Engineering Contradiction:
Improvecrosslinking speedVSAvoidscorch time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent employs a two-stage acceleration mechanism where the peptide accelerator first provides a controlled induction period allowing safe processing, then activates rapid crosslinking at the desired vulcanization temperature. This periodic action separates the processing phase from the crosslinking phase in time, avoiding premature vulcanization while ensuring fast final curing.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent utilizes temperature-dependent activation of the peptide accelerator. At processing temperatures, the accelerator remains relatively inactive allowing safe handling and shaping. Upon reaching vulcanization temperature, the peptide undergoes conformational changes or decomposition that activates its accelerating function, triggering rapid crosslinking only when desired.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If quaternary ammonium salts are used as accelerators, then safety is improved, but vulcanization efficiency and scorch time control are insufficient

Engineering Contradiction:
ImprovesafetyVSAvoidvulcanization efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent creates a composite accelerator system combining the safe biodegradable peptide structure with functional groups that provide efficient vulcanization activity. The peptide backbone ensures safety and biodegradability, while incorporated sulfur-containing or metal-coordinating moieties provide the necessary crosslinking acceleration, achieving both safety and efficiency in a single compound.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The peptide accelerator serves multiple functions simultaneously: it acts as a vulcanization accelerator, a processing aid that controls scorch time, and a biodegradable carrier that ensures environmental safety. The single compound integrates functions that traditionally required multiple separate additives, achieving universality in performance while maintaining safety.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves rapid and controlled vulcanization with extended scorch times, improved dynamic mechanical properties, and reduced silica interaction, enhancing tire performance and safety by avoiding toxic compounds and migration issues.

Implementation Method 1

vulcanization is a process that produces chemical crosslinks between polymer chains. In the case of vulcanization, i.e. sulphur-based crosslinking, a crosslink may be formed by a group of sulphur atoms in a short chain or by a single sulphur atom

Methodology Applied
Scientific EffectVulcanization: Chemical Bonding

Implementation Method 2

effectively disperses silica, reducing the Payne effect and migration

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS11091608B2Elastomeric composition and vulcanization accelerator used therein
Publication Date: 2021.08.17 PIRELLI TYRE SPA
  • US11091608B2 patent drawing
  • US11091608B2 patent drawing
  • US11091608B2 patent drawing

AI summary

The present invention relates to a vulcanizable elastomeric composition comprising a secondary accelerator that may be used in combination with sulphenamide alone, completely avoiding the use of a guanidine. Moreover, said accelerator promotes dispersion of the silica in the compound and migrates with difficulty in the elastomeric composition itself. The invention also relates to the use of a vulcanization accelerator for said elastomeric composition, to the associated vulcanization process and to a tyre comprising same.