Percolating Source Layer for Low-Voltage OFET Memory

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Solution Overview

Problem

Existing semiconductor devices face challenges in achieving low write and erase voltages while maintaining fast reading speeds and stable hysteresis characteristics, particularly in organic field-effect transistors (OFETs) due to limitations in charge injection mechanisms and material compatibility.

Innovation Solution

The semiconductor device incorporates an electrically percolating source layer, such as a dilute network of carbon nanotubes, a memory layer with charge storage materials like benzocyclobutene, and a Schottky barrier configuration that allows direct charge injection from the source layer to the memory layer, reducing the reliance on the semiconducting channel for voltage control and enhancing hysteresis characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional charge injection mechanisms are used in organic field-effect transistors, then device structure is simple, but write and erase voltages are high and hysteresis characteristics are unstable

Engineering Contradiction:
Improvehysteresis characteristicsVSAvoidwrite and erase voltages
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

An electrically percolating source layer is introduced as an intermediary between the electrode and the semiconducting channel. This source layer, composed of materials such as carbon nanotubes, metallic nanowires, or conductive polymers, enables direct charge injection into the memory layer while maintaining electrical continuity, thereby reducing the voltages required for write and erase operations and stabilizing hysteresis characteristics.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The source layer utilizes composite material structures, such as dilute networks of carbon nanotubes or combinations of metallic and semiconducting nanowires, which provide both electrical conductivity and controlled charge injection properties. These composite materials enable efficient charge transfer to the memory layer without requiring high voltages, resolving the contradiction between energy consumption and reliability.

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If direct charge injection from source layer to memory layer is implemented, then write and erase voltages are reduced, but device complexity increases

Engineering Contradiction:
Improvewrite and erase voltagesVSAvoiddevice structure
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The device is segmented into distinct functional layers: an electrically percolating source layer, a memory layer with charge storage materials, and a semiconducting channel layer. This segmentation allows each layer to perform its specific function efficiently, with the source layer handling charge injection and the memory layer storing charges, thereby reducing the overall voltages required while maintaining manageable device complexity through clear functional separation.

Inventive Principle:
Principle #1Segmentation

3Productivity

If carbon nanotube network is used as source layer, then charge injection efficiency is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improvecharge injection efficiencyVSAvoidnanotube network formation
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The manufacturing process utilizes parameter changes, specifically controlling the concentration and distribution of carbon nanotubes in the source layer to achieve the desired electrical percolation threshold. By adjusting parameters such as nanotube density, length, and spatial distribution, efficient charge injection is achieved without requiring extremely precise manufacturing control, as the system tolerates a range of parameter values that maintain percolation and conductivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enables lower write and erase voltages, faster reading speeds, and improved ON/OFF current ratios, along with enhanced hysteresis stability, making the device suitable for both memory and transistor applications with reduced power consumption and increased flexibility in material selection.

Implementation Method 1

The source layer is an electrically percolating layer such as, e.g., a dilute network of carbon nanotubes (CNTs), a layer of graphene, a dilute network of metallic and/or semiconducting nanowires, or a layer of a conductor, semiconductor, or semi-metal including perforations

Methodology Applied
Scientific EffectElectrical percolation: Conduction (electrical)

Implementation Method 2

The semiconductor device is configured to utilize a field effect controlled Schottky barrier at the interface between the source layer and the semiconducting channel layer in order to turn the device on and off

Methodology Applied
Scientific EffectSchottky barrier: Electrical Resistance

Implementation Method 3

a memory layer with charge storage materials like benzocyclobutene

Methodology Applied
Scientific EffectCharge storage: Capacitance

Data Source

PatentEP2543086B1Semiconductor devices including an electrically percolating source layer and methods of fabricating the same
Publication Date: 2019.06.19 UNIV OF FLORIDA RESEARCH FOUNDATION INC
  • EP2543086B1 patent drawingFigure 1~2
  • EP2543086B1 patent drawingFigure 3~4
  • EP2543086B1 patent drawingFigure 5~6

AI summary

Various embodiments are provided for semiconductor devices including an electrically percolating source layer and methods of fabricating the same. In one embodiment, a semiconductor device includes a gate layer, a dielectric layer, a memory layer, a source layer, a semiconducting channel layer, and a drain layer. The source layer is electrically percolating and perforated. The semiconducting channel layer is in contact with the source layer and the memory layer. The source layer and the semiconducting channel layer form a gate voltage tunable charge injection barrier.