Chemically-Selective Percolation Switch for Ultra-Low Power Chemical Analysis

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Solution Overview

Problem

Existing chemical sensors and electronic nose technologies face challenges in achieving simultaneous chemical selectivity and ultra-low power consumption, limiting their ability to operate at sub-10 nW or nearly-zero power, which restricts their distribution due to limited battery lifetime and high power consumption.

Innovation Solution

The development of chemically-selective percolation switches and sensors that utilize a binding agent in a switch gap between electrodes, allowing for the formation of an electrically conductive pathway only when a target chemical compound reaches a certain threshold concentration, enabling zero or near-zero power consumption by 'sleeping' when the chemical is below the threshold and 'waking up' upon detection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional chemical sensors operate continuously to maintain chemical selectivity, then detection capability is improved, but power consumption increases beyond ultra-low levels

Engineering Contradiction:
Improvechemical selectivityVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The sensor operates in periodic cycles between sleep mode and active detection mode. The binding agent layer accumulates target chemicals during sleep mode, then triggers a detection event when threshold concentration is reached, enabling periodic rather than continuous operation while maintaining selectivity through the binding agent's specific chemical affinity.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The binding agent layer performs preliminary action by pre-concentrating and selectively binding target chemicals to the sensor surface before detection. This pre-processing step accumulates analytes during low-power sleep mode, so that when detection activates, the threshold is already met, eliminating the need for continuous high-power operation.

Inventive Principle:
Principle #10Preliminary action

2Measurement precision

If chemical sensors operate at elevated temperatures to enhance sensitivity, then detection sensitivity is improved, but power consumption increases due to heater requirements

Engineering Contradiction:
Improvedetection sensitivityVSAvoidpower consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The patent replaces the thermal field (heater-based temperature elevation) with a chemical field approach. Instead of using heat to enhance sensor-s analyte interaction, the binding agent provides chemical selectivity and concentration enhancement at room temperature, eliminating the need for high-power heating elements while maintaining detection sensitivity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the operating temperature parameter from elevated temperatures (required by conventional sensors) to room temperature. This parameter change is enabled by the binding agent mechanism, which provides sufficient selectivity and concentration effect without thermal activation, thereby reducing power consumption while maintaining measurement precision.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If sensors use pattern recognition electronics to achieve target selectivity, then chemical selectivity is improved, but device complexity and power consumption increase

Engineering Contradiction:
Improvechemical selectivityVSAvoidelectronics complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The binding agent layer serves as an intermediary that performs the selectivity function before the signal reaches the electronics. By placing the chemical recognition function in the physical binding agent layer rather than in electronic pattern recognition circuits, the system achieves selectivity with minimal electronic complexity and ultra-low power consumption.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces electronic pattern recognition systems with a chemical recognition mechanism. The binding agent's molecular specificity provides target selectivity without requiring complex electronic processing, thereby eliminating the need for high-power microprocessors and pattern recognition algorithms while maintaining chemical selectivity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Reliability

If conductivity sensors use metal oxide membranes for gas detection, then chemical selectivity is improved, but power consumption increases due to high temperature operation

Engineering Contradiction:
Improvechemical selectivityVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The sensor uses a composite structure combining an inert substrate with a functional binding agent layer. The binding agent layer contains specific chemical moieties tailored for target recognition, while the substrate provides mechanical support. This composite approach enables room temperature operation with high selectivity, replacing the high-temperature metal oxide membrane system.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly extends the battery life of chemical sensors by eliminating static power consumption, allowing them to operate nearly zero-power when no target chemical is present, and dramatically increases their operational lifetime without the need for frequent battery replacements.

Implementation Method 1

The binding sites can be distributed in the switch gap such that the binding sites are capable of binding molecules of the target chemical compound to form an electrically conductive pathway via percolation between the positive electrode and the negative electrode

Methodology Applied
Scientific EffectPercolation:

Implementation Method 2

A binding agent can be located at a plurality of binding sites in the switch gap. The binding agent can be selective for binding a target chemical compound

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS10502725B2Ultra-low power digital chemical analyzers
Publication Date: 2019.12.10 UNIV OF UTAH RES FOUND
  • US10502725B2 patent drawing
  • US10502725B2 patent drawing
  • US10502725B2 patent drawing

AI summary

A zero-power digital chemical analyzer can include a chemically-selective percolation switch. The chemically selected percolation switch can include a positive electrode and a negative electrode separated from the positive electrode by a gap. A binding agent can be located at binding sites in the gap. The binding agent can be selective for binding to a target chemical compound. The binding sites can be distributed in the gap so that target chemical molecules binding to the binding sites can form an electrically conductive pathway via a natural percolation phenomenon between the electrodes when the ambient concentration of the target chemical compound reaches a threshold concentration.