Perfluoroalkene Solvent for Fluorine Resin Optical Fiber Purity

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Solution Overview

Problem

Existing fluorine-containing resin compositions used in plastic optical fibers (POFs) face challenges in reducing environmental impact and impurity intrusion during processing, with conventional solvents having high global warming potential and allowing significant elution of process materials.

Innovation Solution

A fluorine-containing resin composition using perfluoroalkene as the solvent, which has a lower global warming potential and does not elute process materials, combined with a fluorine-containing polymer structure that enhances solubility and filterability, reducing impurity intrusion and environmental impact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional solvents are used in fluorine-containing resin compositions, then the resin can be dissolved and processed, but the global warming potential increases and process materials elute into the composition

Engineering Contradiction:
Improvesolubility and processability of fluorine-containing resinVSAvoidenvironmental impact and impurity intrusion
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the solvent from conventional fluorinated solvents to perfluoroalkenes, which have different molecular structures and properties. This parameter change results in lower environmental impact and reduced elution of process materials while maintaining the ability to dissolve fluorine-containing resins for optical fiber manufacturing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The perfluoroalkene solvent is designed to be used in a controlled manufacturing process where it can be easily removed or replaced after serving its purpose of dissolving the resin and enabling filtration, rather than remaining as a permanent component in the final optical fiber product

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Manufacturing precision

If filtration is performed to remove foreign matter from fluorine-containing resin, then optical quality improves, but process materials may be lost or contaminated

Engineering Contradiction:
Improveoptical quality and purity of resinVSAvoidloss of resin material during filtration
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

The perfluoroalkene solvent acts as an intermediary that enables effective filtration by dissolving the fluorine-containing resin and keeping it in solution during the filtration process. This allows foreign matter to be removed while the resin remains dissolved and can be recovered after filtration, minimizing material loss

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent utilizes the specific solubility parameters of perfluoroalkenes to maintain resin in solution during filtration, changing the physical state and flow properties of the resin to enable effective separation of impurities while preventing resin deposition or loss in the filtration system

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves reduced environmental impact and improved filterability, effectively minimizing impurity intrusion and process material elution, while maintaining high solubility and resin quality.

Implementation Method 1

a solvent in which the fluorine-containing resin is dissolved, wherein the solvent is a perfluoroalkene

Methodology Applied
Scientific EffectSolvation: Solvation

Data Source

PatentUS20250110260A1Fluorine-containing resin composition for plastic optical fibers, plastic optical fiber or resin rod for plastic optical fibers, and method for manufacturing resin formed body for plastic optical fibers
Publication Date: 2025.04.03 NITTO DENKO CORP
  • US20250110260A1 patent drawing
  • US20250110260A1 patent drawing
  • US20250110260A1 patent drawing

AI summary

A fluorine-containing resin composition of the present invention includes: a fluorine-containing resin; and a solvent in which the fluorine-containing resin is dissolved. The solvent is a perfluoroalkene. The fluorine-containing resin includes a fluorine-containing polymer including a structural unit (A) represented by the following formula (1).(In the formula (1), Rff1 to Rff4 each independently represent a fluorine atom, a perfluoroalkyl group having 1 to 7 carbon atoms, or a perfluoroalkyl ether group having 1 to 7 carbon atoms. Rff1 and Rff2 are optionally linked to form a ring.)