Perfluoropolyether Coating Resists Water Scale and Oil

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Solution Overview

Problem

Conventional stain-resistant coating materials for sanitary ceramic wares and glass products are prone to oily component adhesion, leading to contaminant accumulation, and fail to effectively resist both water scale and oily components when exposed to water containing soluble silica.

Innovation Solution

A stain-resistant coating material comprising a perfluoropolyether main agent, an alkane solvent with a mean molecular weight of 138 to 180 g/mol, and a fluorine-based solvent, such as hydrofluoroether, which shields hydroxyl groups and prevents oily component adhesion, while maintaining stability and reactivity with hydrochloric acid as a catalyst.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional stain-resistant coating material is applied, then water scale resistance is improved, but oily component adhesion increases

Engineering Contradiction:
Improvewater scale resistanceVSAvoidoily component adhesion
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the coating material by incorporating perfluoropolyether and specific alkane solvents with controlled molecular weights (138-180 g/mol). This parameter modification transforms the coating's surface properties to simultaneously achieve water scale resistance and oily component repellency, resolving the contradiction between water scale resistance and oily component adhesion.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite coating material combining perfluoropolyether main agent, hydrofluoroether solvent, and specific alkane solvent. This composite formulation integrates the water-resistant properties of perfluoropolyether with the oil-repellent characteristics of the alkane-alkene complex, achieving dual functionality that resolves the contradiction between resisting water scale and preventing oily component adhesion.

Inventive Principle:
Principle #40Composite materials

2Reliability

If perfluoroalkyl group-containing organosilicon compound is used, then water scale resistance is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvewater scale resistanceVSAvoidcoating material preparation
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent simplifies manufacturing by changing the chemical structure parameters to perfluoropolyether, which has inherent stability and reactivity characteristics that eliminate the need for complex co-hydrolysis processes. The use of hydrofluoroether as solvent further simplifies the formulation, reducing manufacturing complexity while maintaining water scale resistance.

Inventive Principle:
Principle #35Parameter changes

3Speed

If strong acid catalyst is used, then reactivity is improved, but stability decreases

Engineering Contradiction:
Improvereaction speedVSAvoidcoating material stability
Core Design Contradiction:
SpeedVSStability of the object's composition

Solution Approach 1:

The patent changes the catalyst system from strong acids to hydrochloric acid at controlled concentrations (0.1-1.0 g/L), optimizing the balance between reactivity and stability. This parameter adjustment provides sufficient reaction speed for coating formation while maintaining composition stability during storage and application, resolving the contradiction between reaction speed and composition stability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enhances both water scale and oily component resistance in sanitary ceramic wares and glass products, maintaining a clean and smooth appearance over time by preventing hydroxyl group interaction with soluble silica and oily components.

Implementation Method 1

the stain-resistant layer shields the hydroxyl groups present on the surface of the glaze layer or glass, and shields the hydroxyl groups to make them incompetent

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

oily components do not easily stick to the stain-resistant layer

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 3

a perfluoropolyether main agent, and a solvent including an alkane and an alcohol... with hydrochloric acid as a catalyst

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS8865815B2Stain-resistant coating material and product having glass layer
Publication Date: 2014.10.21 LIXIL CORP
  • US8865815B2 patent drawing
  • US8865815B2 patent drawing
  • US8865815B2 patent drawing

AI summary

The invention is intended to easily enhance both the stain-resistant property against water scale and the stain-resistant property against oily components, in sanitary ceramic wares and the like which are brought into contact with water containing soluble silica as well as oily components. The stain-resistant coating material of the invention contains a main agent formed from a perfluoropolyether, and a solvent including an alkane and an alcohol, while the alkane has mean molecular weight of 138 to 180 g/mol.