Perfluoropolyether Silane Surface Treating Agent for Friction Durability

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Solution Overview

Problem

Conventional surface-treating agents containing fluoro-containing silane compounds lack sufficient friction durability for applications requiring long-term functionality, especially in optical members and touch panels that need to maintain light permeability and transparency.

Innovation Solution

A surface-treating agent comprising a perfluoro(poly)ether group containing silane compound with 80 mol% or more of the repeating units of polyethylene chains having a Si atom in its side chain, specifically formulated to enhance friction durability while maintaining water-repellency, oil-repellency, and antifouling properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional surface-treating agent containing fluoro-containing silane compound is used, then water-repellency and oil-repellency are achieved, but friction durability is insufficient

Engineering Contradiction:
Improvefriction durabilityVSAvoidlong-term functionality
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The invention changes the molecular structure parameters of the silane compound by specifying that g (number of repeating units of polyethylene chain having Si atom) must be 2 or more, and this structure must constitute 80 mol% or more of the total. This parameter change in molecular architecture directly improves friction durability while maintaining the duration of action

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite molecular structure combining perfluoropolyether main chain with multiple polyethylene chains containing Si atoms. This composite structure at the molecular level provides both the water/oil repellency (from fluorine) and enhanced friction durability (from multiple Si-containing chains), resolving the contradiction between initial performance and long-term durability

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If the surface-treating layer is made thin to maintain light permeability, then transparency is improved, but friction durability decreases

Engineering Contradiction:
Improvelight permeabilityVSAvoidfriction durability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The invention changes the molecular structure parameters to achieve higher functionality per unit thickness. By specifying g≥2 and the 80 mol% composition requirement, the compound provides enhanced friction durability in a thinner film, thus maintaining light permeability while improving reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention concentrates the friction-resistant functionality in specific molecular regions (the polyethylene chains with Si atoms at g≥2) that constitute 80 mol% or more of the structure. This localized quality enhancement allows thin films to achieve high friction durability without compromising light permeability

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The novel surface-treating agent forms a layer with improved friction durability, water-repellency, oil-repellency, and antifouling properties, suitable for use in optical members and touch panels, ensuring long-term functionality and resistance to fouling and water infiltration.

Implementation Method 1

a perfluoro(poly)ether group containing silane compound comprising a main molecular chain having a perfluoropolyether group and a polyethylene chain having a Si atom having a hydroxyl group or a hydrolyzable group in its side chain

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

The layer formed from the surface-treating agent containing the fluoro-containing silane compound

Methodology Applied
Scientific EffectCondensation:

Implementation Method 3

A certain fluorine-containing silane compound is known to be able to provide excellent water-repellency, oil-repellency, antifouling property

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Data Source

PatentEP3088487B1Surface treating agent including perfluoro(POLY)ether-group-containing silane compound
Publication Date: 2021.05.05 DAIKIN INDUSTRIES LTD
  • EP3088487B1 patent drawing
  • EP3088487B1 patent drawing
  • EP3088487B1 patent drawing

AI summary

The present invention provides a surface-treating agent comprising at least one perfluoro(poly)ether group containing silane compound of the formula (1): wherein the symbols have the same definition as set forth in description.