Perfluoropolyether Silane with UV Absorbing Groups

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Solution Overview

Problem

The surface-treating layers formed from existing fluorine-containing silane compounds lack durability, particularly against ultraviolet light exposure, leading to insufficient light stability and ultraviolet resistance.

Innovation Solution

Incorporating a radical scavenger group or ultraviolet ray absorbing group into the molecular chain of perfluoro(poly)ether group containing silane compounds to enhance light stability and ultraviolet resistance, specifically using benzophenones, benzotriazoles, or other UV-absorbing residues.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fluorine-containing silane compound is used for surface treatment, then water-repellency and oil-repellency are improved, but light stability and ultraviolet resistance deteriorate

Engineering Contradiction:
Improvelight stabilityVSAvoidultraviolet resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention combines fluorine-containing silane compound with UV-absorbing groups (such as benzotriazole, benzophenone, triazine, or salicylate groups) to create a composite surface treatment agent. This composite structure allows the material to simultaneously provide water-repellency from the fluorine-containing component and ultraviolet resistance from the UV-absorbing groups, resolving the contradiction between hydrophobicity and light stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The surface treatment agent is designed to perform multiple functions simultaneously: the fluorine-containing silane portion provides water-repellency and oil-repellency, while the incorporated UV-absorbing groups provide ultraviolet resistance and light stability. This multi-functional design eliminates the need for separate treatments and achieves both properties in a single coating layer.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Duration of action of stationary object

If fluorine-containing silane compound is applied as surface-treating layer, then water-repellency is improved, but durability against ultraviolet light exposure deteriorates

Engineering Contradiction:
ImprovedurabilityVSAvoidultraviolet resistance
Core Design Contradiction:
Duration of action of stationary objectVSObject-affected harmful factors

Solution Approach 1:

By creating a composite surface treatment agent that integrates fluorine-containing silane with UV-absorbing chromophores, the invention achieves long-term durability against ultraviolet exposure. The UV-absorbing groups act as molecular sunscreens, absorbing harmful UV radiation before it can degrade the fluorine-containing layer, thereby extending the service life of the water-repellent coating.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The UV-absorbing groups are incorporated into the surface treatment agent structure in advance, providing preemptive protection against ultraviolet damage. These groups absorb UV energy before it can reach and degrade the fluorine-containing silane network, cushioning the main functional layer against environmental degradation and maintaining durability over time.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modified perfluoro(poly)ether group containing silane compounds form surface-treating layers with improved water-repellency, oil-repellency, antifouling properties, and high ultraviolet resistance, maintaining performance over time.

Implementation Method 1

Incorporating a radical scavenger group or ultraviolet ray absorbing group into the molecular chain of perfluoro(poly)ether group containing silane compounds to enhance light stability and ultraviolet resistance

Methodology Applied
Scientific EffectUltraviolet absorption: Absorption (EM radiation)

Data Source

PatentEP3345955B1Perfluoro(POLY)ether group-containing silane compound
Publication Date: 2022.04.06 DAIKIN INDUSTRIES LTD
  • EP3345955B1 patent drawing
  • EP3345955B1 patent drawing
  • EP3345955B1 patent drawing

AI summary

The present invention provides a perfluoro(poly)ether group containing silane compound of the formula (1):         XRaαRbβRcγ ···     (1) wherein each symbols are as defined in the description.