Perovskite Capacitor Electrode Stabilization

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Solution Overview

Problem

As semiconductor devices miniaturize, the capacitance of capacitors decreases and leakage current increases, posing challenges in maintaining effective dielectric characteristics and stability of perovskite crystal structures in capacitors.

Innovation Solution

A capacitor design featuring a dielectric layer with a perovskite crystal structure, sandwiched between electrodes with metallic, semiconductor, and ionic layers, where the metallic layer has a thickness of 50 Å or less, and the semiconductor layer is five times thicker, stabilizing the dielectric layer's crystallinity and enhancing capacitance characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the size of the capacitor is reduced for miniaturization, then the degree of integration improves, but the capacitance decreases and leakage current increases

Engineering Contradiction:
Improvedegree of integrationVSAvoidcapacitance characteristics
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the material composition parameters of the electrode, introducing a multi-layer structure with metallic layer (50 Å or less), semiconductor layer (five times or more thicker than metallic layer), and ionic layer. This parameter change in material composition enables maintaining high capacitance characteristics even in miniaturized capacitors.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining metallic layer, semiconductor layer, and ionic layer in a multi-layer electrode structure. This composite approach allows the electrode to simultaneously provide conductivity, charge storage, and interface stability, resolving the contradiction between miniaturization and capacitance maintenance.

Inventive Principle:
Principle #40Composite materials

2Length of stationary object

If the size of the capacitor is reduced, then the device dimensions decrease, but the leakage current increases

Engineering Contradiction:
Improvecapacitor sizeVSAvoidleakage current
Core Design Contradiction:
Length of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The patent changes the electrode material parameters by introducing a multi-layer structure with specific thickness ratios (semiconductor layer five times or more thicker than metallic layer). This parameter optimization reduces leakage current while maintaining small capacitor size.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The semiconductor layer acts as an intermediary between the metallic layer and the dielectric layer, providing a transition zone that reduces leakage current. The ionic layer further mediates the interface between electrode and dielectric, stabilizing the structure and minimizing harmful leakage effects in miniaturized capacitors.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Device complexity

If a simple electrode structure is used, then the device complexity is reduced, but the perovskite crystal structure stability deteriorates

Engineering Contradiction:
Improveelectrode structureVSAvoidperovskite crystal structure
Core Design Contradiction:
Device complexityVSStability of the object's composition

Solution Approach 1:

The patent uses composite materials with a multi-layer electrode structure (metallic layer, semiconductor layer, ionic layer) that provides the necessary stability for perovskite crystal structure. The specific thickness ratios and material combinations create a stable interface that maintains crystallinity without excessive complexity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by assigning different functions to different layers: the metallic layer provides conductivity, the semiconductor layer provides charge storage and interface stability, and the ionic layer provides chemical stability. This localized functional distribution stabilizes the perovskite structure while keeping the overall design manageable.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The design stabilizes the perovskite crystal structure, improves capacitance, and reduces leakage current, resulting in a capacitor with enhanced dielectric constant and capacitance characteristics.

Implementation Method 1

a dielectric layer having a perovskite crystal structure between the first and second electrodes, wherein at least one of the first and second electrodes includes a metallic layer having a perovskite crystal structure

Methodology Applied
Scientific EffectPerovskite crystal structure:

Data Source

PatentEP4216692A1Capacitor and semiconductor device including the capacitor
Publication Date: 2023.07.26 SAMSUNG ELECTRONICS CO LTD
  • EP4216692A1 patent drawingFigure 1
  • EP4216692A1 patent drawingFigure 2
  • EP4216692A1 patent drawingFigure 3

AI summary

Provided are a capacitor and a semiconductor device including the same. The capacitor includes: a dielectric layer having a perovskite crystal structure; and first and second electrodes spaced apart from each other with the dielectric layer therebetween. At least one of the first and second electrodes includes a metallic layer having a perovskite crystal structure, a first ionic layer having ionic properties, and a semiconductor layer.