Lead-Free Perovskite Gain Medium for Low-Cost On-Chip Lasers

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Solution Overview

Problem

Current laser technologies rely on costly high-temperature growth techniques for high-quality gain media, limiting their widespread application and integration with various resonator designs, especially for on-chip integration and flexible substrates.

Innovation Solution

The development of a low-temperature solution-processable halide semiconductor material, specifically a lead-free perovskite material, is used as a gain medium in emission sources, which can be easily integrated into a wide range of resonator designs and substrates, including flexible ones, using methods like spin-coating and drop-casting.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high-quality crystalline gain materials are used, then optical amplification performance is improved, but production cost and manufacturing complexity increase due to expensive high temperature growth and high vacuum techniques

Engineering Contradiction:
Improveoptical amplification performanceVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the manufacturing parameters from high temperature and high vacuum conditions to low temperature and ambient pressure conditions. Specifically, it uses solution-based methods at temperatures below 100°C to deposit perovskite gain media, replacing the conventional high temperature crystal growth techniques, thereby dramatically reducing production cost and manufacturing complexity while maintaining optical amplification performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces complex mechanical vacuum systems and high temperature furnaces with simple solution deposition processes. Instead of using molecular beam epitaxy or chemical vapor deposition requiring high vacuum equipment, the invention uses spin-coating or drop-casting methods that can be performed in ambient conditions, substituting complex mechanical systems with simpler chemical processes

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If conventional gain media are used, then optical amplification is achieved, but adaptability to different resonator designs and substrates is limited due to rigid fabrication requirements

Engineering Contradiction:
Improveoptical amplificationVSAvoidintegration with resonator designs
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent creates a universal gain media fabrication method that can be applied to multiple substrate types and resonator configurations. The solution-processable perovskite materials can be deposited on flexible substrates, rigid substrates, and integrated with various resonator designs (micro-ring, micro-disk, photonic crystal) using the same spin-coating or drop-casting process, providing multi-functionality and broad adaptability

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent changes the physical state and processing parameters of the gain media from solid crystalline materials requiring high temperature growth to solution-based soft materials that can be processed at low temperatures. This parameter change enables integration with flexible substrates and diverse resonator geometries that would be incompatible with conventional rigid crystal growth methods

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces production costs, enables efficient coherent light emission with low trap density, and achieves amplified spontaneous emission at ultralow thresholds, making it suitable for on-chip integration and diverse optical cavity designs.

Implementation Method 1

A laser (acronym for light amplification by stimulated emission of radiation) emits coherent light through a process of optical amplification via the stimulated emission of electromagnetic radiation

Methodology Applied
Scientific EffectStimulated emission: Laser

Implementation Method 2

The halide semiconductor material may include a lead-free perovskite material

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS9899793B2Emission source and method of forming the same
Publication Date: 2018.02.20 NANYANG TECH UNIV
  • US9899793B2 patent drawing
  • US9899793B2 patent drawing
  • US9899793B2 patent drawing

AI summary

In various embodiments, an emission source may be provided. The emission source may also include a gain medium including a halide semiconductor material. The emission source may further include a pump source configured to provide energy to the gain medium. The halide semiconductor material may include a lead-free perovskite material.