Peroxide-Catalyzed Cleaning Compositions for Rapid Starch Removal

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Solution Overview

Problem

Existing dishwashing technologies face challenges in efficiently removing starch and other food soils, particularly in professional and fast dishwashing processes, often requiring highly caustic detergents and additional alkaline or acid treatments to prevent starch layer buildup.

Innovation Solution

A composition comprising a detergent with a peroxidation catalyst and a rinse aid containing an oxygen source, such as hydrogen peroxide, is used to enhance soil removal, particularly starch, by catalyzing oxidation reactions under alkaline conditions, reducing the need for additional chemical treatments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If highly caustic detergent is used to remove starch soil, then starch removal efficiency is improved, but chemical complexity and environmental impact increase

Engineering Contradiction:
Improvestarch removal efficiencyVSAvoidchemical complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent employs peroxide compounds (such as hydrogen peroxide, sodium percarbonate, or sodium perborate) as strong oxidants to degrade starch and food soils. The peroxide acts as an oxygen donor that oxidizes organic compounds, breaking down starch molecules into simpler substances. This oxidation mechanism provides effective starch removal without requiring highly caustic chemicals, thus reducing chemical complexity while maintaining high productivity.

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Solution Approach 2:

The patent utilizes temperature as a key parameter to enhance the effectiveness of peroxide-based oxidation. By operating at elevated temperatures (typically 40-70°C), the oxidation reactions proceed more rapidly and efficiently, improving starch removal performance. This parameter change allows the system to achieve high productivity using milder chemicals rather than highly caustic detergents.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If additional alkaline or acid treatments are applied to prevent starch layer buildup, then starch layer prevention is improved, but washing time and process complexity increase

Engineering Contradiction:
Improvestarch layer preventionVSAvoidwashing time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent incorporates rinsing aids that contain metal complexes (such as manganese or iron complexes) capable of catalyzing peroxide decomposition continuously throughout the rinsing phase. This ensures that the oxidation action continues uninterrupted during the rinse cycle, preventing starch layer formation on freshly cleaned surfaces. The continuous catalytic action eliminates the need for separate post-washing treatments, maintaining reliability while minimizing time loss.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The rinsing aid acts as an intermediary substance that bridges the washing and rinsing phases. It contains metal complexes that mediate the peroxide decomposition reaction, ensuring that protective oxidation continues during the rinse cycle. This intermediary mechanism prevents starch layer buildup without requiring additional alkaline or acid treatments, thus avoiding extra time consumption.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If peroxide and catalyst are used together, then soil removal efficiency is improved, but storage stability decreases

Engineering Contradiction:
Improvesoil removal efficiencyVSAvoidstorage stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent divides the cleaning system into separate functional components: a detergent containing the peroxide compound and a separate rinsing aid containing the metal catalyst. These components are stored separately to maintain stability, as the catalyst would otherwise accelerate peroxide decomposition during storage. During the washing process, the detergent and rinsing aid are applied in sequence, allowing the catalyst to activate peroxide decomposition at the point of use rather than during storage, thus resolving the contradiction between productivity and stability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The peroxide is provided in advance in the detergent formulation, ready for use. The catalyst is pre-positioned in the rinsing aid. When the rinsing aid is applied after the detergent, the catalyst immediately activates the peroxide decomposition, preparing the oxidizing action for the critical rinsing phase. This preliminary preparation ensures high soil removal efficiency while maintaining storage stability by keeping the catalyst and peroxide separated until needed.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition significantly improves soil removal efficiency, especially with starch, in short washing times, while being cost-effective and environmentally friendly, minimizing chemical usage and preventing soil redeposition.

Implementation Method 1

a detergent with a peroxidation catalyst and a rinse aid containing an oxygen source, such as hydrogen peroxide, is used to enhance soil removal, particularly starch, by catalyzing oxidation reactions under alkaline conditions

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

catalyzing oxidation reactions under alkaline conditions

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS20250223522A1Compositions and methods for removing soil from surfaces
Publication Date: 2025.07.10 ECOLAB USA INC
  • US20250223522A1 patent drawing

AI summary

The present invention relates to an aqueous composition for removing soils from a surface to be cleaned, formed from water, a detergent mixture and a rinse aid, wherein the detergent mixture comprises a peroxidation catalyst and wherein the rinse aid comprises an oxygen source. Such a composition may provide a more effective cleaning behaviour. The present invention further relates to a method for removing soil from a surface to be cleaned comprising applying to the surface to be cleaned a composition according to the invention.