Shelf-Stable Hydrogen Peroxide Disinfectant via Sulfonic Acid Stabilization

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Solution Overview

Problem

Existing hydrogen peroxide disinfectant solutions face challenges in being effective at high dilution ratios, non-toxic, non-corrosive, biodegradable, and environmentally friendly while maintaining stability and efficacy.

Innovation Solution

A shelf-stable, concentrated antimicrobial solution comprising hydrogen peroxide, readily biodegradable anionic surfactants, salicylic acid, chelating agents, and low-corrosive sulfonic acids, with optional nonionic surfactants and glycol ether solvents, formulated to be free of volatile organic compounds and optimized for pH and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrogen peroxide concentration is increased to maintain effectiveness at high dilution ratios, then antimicrobial efficacy is improved, but corrosiveness and hazard to handle increases

Engineering Contradiction:
Improveantimicrobial efficacyVSAvoidcorrosiveness
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent formulates hydrogen peroxide solutions at optimized concentrations (1.5%-8% w/w) with controlled pH (0-3.5) to balance antimicrobial efficacy with reduced corrosiveness and improved safety for handling, while maintaining stability through this parameter optimization

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces stabilizing agents including chelating agents (0.005%-10% w/w), surfactants (10%-30% w/w), and other additives that act as intermediaries to enhance the performance and stability of hydrogen peroxide at lower, safer concentrations, allowing effective dilution ratios without requiring high concentrations

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If hydrogen peroxide concentration is decreased to reduce corrosiveness and improve safety, then handling safety is improved, but effectiveness at high dilution ratios deteriorates

Engineering Contradiction:
Improvehandling safetyVSAvoideffectiveness at dilution
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent introduces stabilizing agents including chelating agents (0.005%-10% w/w), surfactants (10%-30% w/w), and other additives that act as intermediaries to enhance the performance and stability of hydrogen peroxide at lower, safer concentrations, allowing effective dilution ratios without requiring high concentrations

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent formulates hydrogen peroxide solutions at optimized concentrations (1.5%-8% w/w) with controlled pH (0-3.5) to balance antimicrobial efficacy with reduced corrosiveness and improved safety for handling, while maintaining stability through this parameter optimization

Inventive Principle:
Principle #35Parameter changes

3Speed

If conventional disinfectants are used to achieve rapid disinfection, then disinfection rate is improved, but volatile organic compounds are emitted or toxic residues are left

Engineering Contradiction:
Improvedisinfection rateVSAvoidvolatile organic compounds and toxic residues
Core Design Contradiction:
SpeedVSObject-generated harmful factors

Solution Approach 1:

The patent employs hydrogen peroxide as a strong oxidant that rapidly disinfects through oxidation of microbial cells, achieving fast disinfection rates while decomposing into water and oxygen without leaving toxic residues or emitting volatile organic compounds

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Solution Approach 2:

The patent converts the typically harmful high concentration of hydrogen peroxide into a benefit by using controlled, optimized concentrations with stabilizing agents that prevent decomposition and maintain efficacy, transforming a hazardous substance into a safe and effective disinfectant

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Stability of the object's composition

If hydrogen peroxide solution is formulated to be stable, then shelf stability is improved, but antimicrobial effectiveness may be compromised

Engineering Contradiction:
Improveshelf stabilityVSAvoidantimicrobial effectiveness
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent introduces stabilizing agents including chelating agents (0.005%-10% w/w), surfactants (10%-30% w/w), and other additives that act as intermediaries to enhance the performance and stability of hydrogen peroxide at lower, safer concentrations, allowing effective dilution ratios without requiring high concentrations

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides effective antimicrobial activity against bacteria, viruses, and fungi at high dilution ratios, is safe to handle, and environmentally friendly, maintaining stability and aesthetic appeal with low corrosion and toxicity.

Implementation Method 1

hydrogen peroxide at a concentration of from about 1.5% w/w to 8% w/w

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

at least one readily biodegradable anionic surfactant in a concentration of from about 10% w/w to about 30% w/w

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 3

at least one chelating agent in a concentration of from about 0.005% w/w to about 10% w/w

Methodology Applied
Scientific EffectChelation:

Data Source

PatentUS10968417B2Shelf-stable hydrogen peroxide antimicrobial compositions
Publication Date: 2021.04.06 DIVERSEY INC
  • US10968417B2 patent drawing
  • US10968417B2 patent drawing

AI summary

A disinfecting solution includes hydrogen peroxide at a concentration of from about 1.5% w/w to 8% w/w; at least one readily biodegradable anionic surfactant in a concentration of from about 10% w/w to about 25% w/w; at least one of salicylic acid and salts thereof, in a concentration of from about 1% w/w to about 8% w/w; at least one chelating agent in a concentration of from about 0.005% w/w to about 10% w/w; and at least one low-corrosive non-surfactant sulfonic acid selected from benzenesulfonic acid, benzene disulfonic acid, xylene sulfonic acid, toluene sulfonic acid, cumene sulfonic acid, sulfosalicylic acid, naphthalene mono- or di-sulfonic acid, methane sulfonic acid, and isethionic acid in a concentration of from about 1% w/w to about 15% w/w. The solution is free of acetic acid, furoic acid, phenylacetic acid, cationic surfactants, amphoteric surfactants, aromatic alcohols, halogen acids, phenols, peracid activators, bleaches, and (optionally) benzoic acid.