PFA Composite Membrane for Semiconductor Wastewater

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Solution Overview

Problem

Current water treatment membranes lack porosity and resistance to high temperatures and strong acids, making them inadequate for semiconductor wastewater treatment, which requires efficient filtration under harsh conditions.

Innovation Solution

A porous composite membrane is developed by blending a fluorine-based polymer with an organic substance, such as polyvinylidene fluoride (PVDF) or perfluoromethyl alkoxy (MFA), in specific weight ratios, and processing the mixture through melt-extrusion to create pores without additional pore-forming processes, achieving porosity and thermal stability suitable for semiconductor wastewater treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fluorine-based polymer membranes are used to achieve resistance to high temperatures and strong acids, then chemical stability is improved, but porosity is reduced making the membranes extremely dense

Engineering Contradiction:
Improveresistance to high temperatures and strong acidsVSAvoidporosity control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent combines fluorine-based polymer (PFA) with organic substance particles to create a composite membrane structure. The fluorine-based polymer provides the chemical stability and temperature resistance, while the organic substance particles create porosity when removed, resolving the contradiction between chemical durability and porosity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent intentionally incorporates organic substance particles as pore-forming agents that are later removed, creating a porous structure within the fluorine-based polymer matrix. This allows the membrane to maintain both chemical stability from the polymer and porosity for filtration functionality

Inventive Principle:
Principle #31Porous materials

2Manufacturing precision

If ceramic materials are used to achieve precise porosity control, then porosity control is improved, but processability deteriorates making them prone to breaking and cracking

Engineering Contradiction:
Improveporosity controlVSAvoidprocessability
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent changes the material parameter from brittle ceramic to flexible fluorine-based polymer, fundamentally altering the mechanical properties while maintaining porosity control through the composite structure approach. This allows easy processing without breaking or cracking

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

By using organic substance particles within the polymer matrix as pore-forming agents, the patent achieves precise porosity control comparable to ceramic materials while maintaining the processability and flexibility of polymer materials

Inventive Principle:
Principle #40Composite materials

3Reliability

If single-component fluorine-based polymer membranes are used to achieve chemical stability, then resistance to strong acids is improved, but porosity is reduced making additional pore-forming processes necessary

Engineering Contradiction:
Improveresistance to strong acidsVSAvoidnumber of processing steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent incorporates organic substance particles into the polymer matrix during the initial mixing stage, before membrane formation. These particles serve as pre-positioned pore-forming agents that will be removed later, eliminating the need for separate pore-forming processes

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The composite structure of fluorine-based polymer and organic substance particles allows porosity to be built into the membrane during manufacturing, combining chemical stability with inherent porosity without requiring additional processing steps

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The membrane exhibits excellent resistance to high temperatures and strong acids, with controlled porosity and pore size, enabling effective wastewater treatment and reducing reliance on imported membrane technologies.

Implementation Method 1

processing the mixture through melt-extrusion to create pores without additional pore-forming processes

Methodology Applied
Scientific EffectMelt-extrusion: Extrusion

Data Source

PatentUS20240181402A1Porous composite membrane formed by blending perfluoroalkoxy alkane (PFA) and organic material, and manufacturing method thereof
Publication Date: 2024.06.06 PUKYONG NAT UNIV IND ACADEMIC COOPERATION FOUND
  • US20240181402A1 patent drawing
  • US20240181402A1 patent drawing
  • US20240181402A1 patent drawing

AI summary

There are provided a porous composite membrane formed by blending perfluoroalkoxy alkane (PFA) with an organic substance, and a manufacturing method thereof. The porous composite membrane is able to have pores easily formed simply by blending a fluorine-based polymer with an organic substance without additional pore-forming processes such as stretching and heating, and exhibit excellent properties in terms of resistance to high temperatures and strong acids due to the use of the fluorine-based polymer as a base material, so it is available for use in semiconductor wastewater treatment that uses strong acids like HF.