PFPE Grease Coating for Quiet Sliding at Extreme Temperatures

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Solution Overview

Problem

Existing grease compositions for sliding members in automobiles and industrial machinery face challenges in maintaining operability and reducing noise across a broad temperature range, particularly at extremely low temperatures, and fail to effectively minimize operating noise in automotive interior parts.

Innovation Solution

A grease composition is developed by combining two types of perfluoropolyethers with specific viscosity ranges and adding a fluororesin powder, along with polyolefin particles, to create a lubricating film that enhances operability and reduces noise across a wide temperature range.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high-viscosity perfluoropolyethers are used to improve lubrication, then lubrication performance is improved, but operability at extremely low temperatures deteriorates

Engineering Contradiction:
Improvelubrication performanceVSAvoidoperability at extremely low temperatures
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The grease composition is segmented into multiple perfluoropolyether components with different viscosity ranges (first component: 10-500 mm²/s, second component: 50-1000 mm²/s), allowing each component to contribute differently to low-temperature operability and high-temperature lubrication performance

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the viscosity parameter by selecting specific kinematic viscosity ranges for each perfluoropolyether component and controlling their weight ratio (30:70 to 70:30), thereby achieving a balanced grease viscosity that provides both low-temperature operability and high-temperature lubrication

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional grease compositions are used to provide lubrication, then lubrication is provided, but operating noise is not reduced

Engineering Contradiction:
ImprovelubricationVSAvoidoperating noise
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention uses a composite grease composition combining perfluoropolyether base oils with fluororesin powder (20-40 wt%) and polyolefin particles (5-20 wt%), where the composite structure provides both lubrication and noise reduction through the combined effects of the different materials

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The fluororesin powder and polyolefin particles act as intermediary substances between the sliding surfaces, forming a lubricating film that reduces both friction and noise generation during operation

Inventive Principle:
Principle #24Intermediary (Mediator)

3Adaptability or versatility

If a broad temperature range operation is required, then versatility is improved, but maintaining consistent performance across temperatures becomes difficult

Engineering Contradiction:
Improvetemperature range operationVSAvoidconsistent performance
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The grease is segmented into multiple perfluoropolyether components with different viscosity characteristics, where the lower-viscosity component maintains fluidity at low temperatures while the higher-viscosity component provides lubrication at high temperatures, ensuring consistent performance across the temperature range

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention optimizes the kinematic viscosity parameters of each component and their weight ratio to achieve a grease that maintains appropriate viscosity and lubrication properties across extreme temperature variations from -40°C to +150°C

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a sliding member with improved operability and reduced noise from extremely low to high temperatures, maintaining effective lubrication and noise reduction, especially in automotive applications.

Implementation Method 1

a grease composition comprising: (A) a perfluoropolyether that has a kinematic viscosity of 2-110 mm2/s, the sum of p and r is 5-50, and the CF(CF3)CF2O and CF2O groups are randomly bonded in the main chain); and (C) a fluororesin powder having a primary particle size ≤1 μm

Methodology Applied
Scientific EffectLubrication: Lubrication

Implementation Method 2

The use of high-viscosity perfluoropolyethers results in poor operability at extremely low temperatures, which is a problem in applications that require good operability at extremely low temperatures such as automobile applications. These documents also do not disclose a method for reducing the operating noise

Methodology Applied
Scientific EffectViscous damping: Viscous Damping

Data Source

PatentEP3633015B1Grease composition and sliding member coated therewith
Publication Date: 2024.03.06 DUPONT TORAY SPECIALTY MATERIALS KK
  • EP3633015B1 patent drawing

AI summary

[Problem] To provide a sliding member which has good operatability in a wide temperature range from extremely low to high temperature, and generates less operating sound on a sliding surface, and a grease composition which is used for the sliding member. [Solution] This grease composition contains (A) a straight-chain perfluoropolyether having a kinematic viscosity of 2-110 mm2/s at 40°C, (B) a branched perfluoropolyether having a kinematic viscosity of 2-100 mm2/s at 40°C, and (C) a fluorocarbon resin powder having a primary particle size of 1 µm or less, wherein the contained amount of the fluorocarbon resin powder is 25-40 wt% with respect to the weight of the grease composition, and the weight ratio of the straight-chain perfluoropolyether (A) to the branched perfluoropolyether (B) is 15:85 to 70:30.