pH-Controlled Solid Laundry Detergent Unit Dose

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Solution Overview

Problem

Water-soluble unit dose articles with solid laundry detergent compositions face limitations in cleaning performance due to space constraints, leading to under-performance and instability issues when attempting to add more detergent, as increasing size compromises convenience and structural stability.

Innovation Solution

A water-soluble unit dose article with a pH-controlled solid laundry detergent composition containing a non-soap anionic surfactant and optical brightener 49, which maintains an equilibrium pH between 6.5 and 8.8, ensuring improved fabric whiteness performance without the need for additional detergent.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If additional detergent composition is added to increase cleaning performance, then cleaning performance is improved, but the unit dose article becomes bigger and less convenient

Engineering Contradiction:
Improvedetergent composition amountVSAvoidconvenience
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent changes the pH parameter of the detergent composition (maintaining equilibrium pH between 6.5-8.5) to optimize the performance of whitening agents. This allows improved cleaning and whiteness performance without increasing the quantity of detergent, thus avoiding the need to enlarge the unit dose article while maintaining convenience.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If additional detergent composition is added to increase cleaning performance, then cleaning performance is improved, but the structural stability of the unit dose article is reduced

Engineering Contradiction:
Improvedetergent composition amountVSAvoidstructural stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

By optimizing the pH parameter of the detergent composition, the patent achieves improved cleaning performance without adding more detergent material. This avoids the need to stretch or enlarge the water-soluble film, thereby maintaining the structural stability and integrity of the unit dose article.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If the unit dose article is made bigger to accommodate more detergent, then cleaning performance is improved, but dissolution is impaired due to increased water soluble film

Engineering Contradiction:
Improvedetergent composition amountVSAvoiddissolution rate
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent optimizes the pH parameter of the detergent composition to enhance cleaning efficiency without increasing the detergent quantity. This avoids the need to increase the water-soluble film size, thereby maintaining fast and complete dissolution properties of the unit dose article.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The pH-controlled composition enhances fabric whiteness and cleaning performance by maintaining the stability and convenience of the unit dose article, providing a more effective wash liquor without the need for increased detergent levels.

Implementation Method 1

Upon exposure to water, the water-soluble film dissolves/disintegrates releasing the laundry detergent composition into the surrounding water

Methodology Applied
Scientific EffectWater solubility: Solvation

Implementation Method 2

the solid composition at 1wt% dilution in deionized water at 20°C, has an equilibrium pH in the range of from 6.5 to 8.8

Methodology Applied
Scientific EffectpH control:

Data Source

PatentEP3415591B1Water-soluble unit dose article comprising a solid laundry detergent composition
Publication Date: 2021.04.28 PROCTER & GAMBLE CO

AI summary

Water-soluble unit dose article containing solid laundry detergent composition and water-soluble film; the solid detergent composition comprises a whitening agent and has a low pH.