pH-Sensitive Nanocomposite CO2 Sensor with Hydrophobic Coating

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current CO2 sensors are costly, affected by humidity, and limited in application, making them unsuitable for widespread use in monitoring CO2 levels in breath and indoor air quality due to their inability to provide accurate, fast, and reversible measurements.

Innovation Solution

A multifunctional CO2 detector using a pH-sensitive nanocomposite material on a microstructured hydrophobic substrate that changes color in response to CO2, coupled with a mobile device interface for real-time data analysis, allowing for breath-by-breath and environmental CO2 monitoring with humidity compensation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If infrared-based CO2 sensors are used, then measurement precision is improved, but device cost increases and humidity interference worsens

Engineering Contradiction:
ImproveCO2 measurement accuracyVSAvoidhumidity interference
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent introduces a hydrophobic coating as an intermediary layer between the CO2 sensor and the humid environment. This coating selectively blocks water molecules while allowing CO2 to pass through and react with the sensing material, thereby eliminating humidity interference without compromising CO2 measurement accuracy

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The sensor surface is modified with a hydrophobic coating that creates localized regions with different permeability properties. The coating maintains high CO2 permeability while providing strong water repellency, allowing the sensor to operate accurately in humid conditions by creating a protective interface at the measurement location

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If colorimetric CO2 sensors are used, then device cost is reduced, but response time is too slow for breath-by-breath monitoring

Engineering Contradiction:
Improvedevice costVSAvoidresponse time
Core Design Contradiction:
Ease of manufactureVSSpeed

Solution Approach 1:

The patent employs a composite sensing material consisting of a hydrophobic polymer matrix combined with pH-sensitive indicator particles. This composite structure provides both the low-cost colorimetric detection capability and the fast response kinetics needed for breath-by-breath monitoring, achieving a response time of less than 1 second

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The sensing layer utilizes a porous hydrophobic polymer structure that allows rapid diffusion of CO2 molecules to the indicator particles embedded within the matrix. The porous architecture increases the surface area and reduces diffusion path lengths, enabling fast response times while maintaining the simplicity and low cost of colorimetric detection

Inventive Principle:
Principle #31Porous materials

3Measurement precision

If CO2 sensors are designed for high sensitivity, then measurement precision is improved, but device complexity increases

Engineering Contradiction:
ImproveCO2 detection sensitivityVSAvoidsensor structure complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent extracts and isolates the humidity-sensitive component by applying a hydrophobic coating that selectively excludes water molecules. This separation allows the CO2 sensing function to operate independently without interference from humidity, achieving high sensitivity through a relatively simple coated structure rather than complex multi-sensor arrangements

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the surface energy parameters of the sensor material by applying a hydrophobic coating, which fundamentally alters the sensor's interaction with water and CO2 molecules. This parameter change enables high sensitivity to CO2 while maintaining simplicity, as the coating passively provides selectivity without requiring complex active control mechanisms

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The detector provides accurate, fast, and reversible CO2 measurements, is cost-effective, and can be used repeatedly, enabling real-time monitoring of CO2 levels in both breath and indoor air quality, overcoming the limitations of existing sensors.

Implementation Method 1

The CO2 sensor uses a new ultra-fast and reversible response pH-sensitive nanocomposite material on a microstructured hydrophobic substrate as a sensor element for CO2 detection, which changes color when exposed to CO2

Methodology Applied
Scientific EffectpH-sensitive color change: Photochromism

Implementation Method 2

a hydrophobic surface

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Data Source

PatentUS10663442B2Specific, reversible, and wide-dynamic range sensor for real time detection of carbon dioxide
Publication Date: 2020.05.26 THE ARIZONA BOARD OF REGENTS ON BEHALF OF THE UNIV OF ARIZONA
  • US10663442B2 patent drawing
  • US10663442B2 patent drawing
  • US10663442B2 patent drawing

AI summary

A method for CO2 detection includes obtaining a gas sample; exposing a CO2 sensor to the gas sample, where the sensor includes a reversible and selective pH-sensitive nanocomposite sensor element for CO2 detection, and a hydrophobic surface; compensating for humidity and temperature; coupling at least one light source to receive signals from the CO2 sensor and respond to color changes in the sensor by transducing the color change into a light intensity change; measuring flow; and receiving signals from the at least one light source by at least one photodiode which responds to light intensity changes by transducing the light intensity changes into electronic signals representing varying degrees of light intensity.