Pharmaceutical Composition Dissolution via Acidifying Agents

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Solution Overview

Problem

The existing pharmaceutical compositions containing compound I exhibit poor dissolution properties in neutral aqueous solutions, which hinders their effectiveness as a therapeutic agent for thrombotic diseases.

Innovation Solution

Adjusting the proportion of compound I in the pharmaceutical composition to 0.5% to 10% by weight and incorporating sugar alcohols and water-swelling additives, along with coating agents like cellulose derivatives and polyvinyl compounds, enhances the dissolution rate in neutral pH conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If compound I is used as an active ingredient in a pharmaceutical composition, then it exhibits potent inhibitory effect on activated factor X, but it shows reduced solubility and poor dissolution properties in neutral aqueous solution

Engineering Contradiction:
Improvetherapeutic effectivenessVSAvoiddissolution rate
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies parameter changes by adjusting the pH of the dissolution medium to create an acidic environment (pH 5.0 or lower) that enhances the solubility and dissolution rate of compound I. This is achieved by incorporating acidifying agents into the pharmaceutical composition, which locally acidify the microenvironment around the drug substance, thereby resolving the contradiction between maintaining therapeutic effectiveness and improving dissolution properties in the physiological pH range.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If compound I is used at higher concentrations to improve therapeutic effect, then potency increases, but dissolution properties in neutral region deteriorate further

Engineering Contradiction:
Improveamount of compound IVSAvoiddissolution rate
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent introduces acidifying agents as intermediary substances that mediate between the drug substance and the dissolution medium. These agents create a localized acidic microenvironment that facilitates dissolution without requiring changes to the bulk pH of the dissolution medium, thereby enabling higher concentrations of compound I to be incorporated while maintaining or improving dissolution properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If conventional coating methods are used to improve dissolution, then dissolution properties are enhanced, but the composition becomes more complex and manufacturing becomes more difficult

Engineering Contradiction:
Improvedissolution rateVSAvoidcomposition complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent merges the functions of dissolution enhancement and stabilization into a single approach by incorporating acidifying agents directly into the pharmaceutical composition matrix. This eliminates the need for separate coating layers or complex multi-component systems, thereby improving dissolution properties while maintaining composition simplicity and ease of manufacturing.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modified composition demonstrates improved dissolution properties in neutral pH, ensuring better bioavailability and therapeutic efficacy as an anticoagulant for treating thrombotic diseases.

Implementation Method 1

incorporating sugar alcohols and water-swelling additives

Methodology Applied
Scientific EffectOsmosis: Osmosis

Implementation Method 2

water-swelling additives

Methodology Applied
Scientific EffectHydration: Hydrates

Implementation Method 3

coating agents like cellulose derivatives and polyvinyl compounds

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2444087B1Pharmaceutical composition having improved solubility
Publication Date: 2016.09.07 DAIICHI SANKYO CO LTD
  • EP2444087B1 patent drawingFigure 1
  • EP2444087B1 patent drawingFigure 2
  • EP2444087B1 patent drawingFigure 3

AI summary

It is desired to provide a pharmaceutical composition containing a compound represented by formula (I) or a pharmacologically acceptable salt thereof, or a solvate thereof, which exhibits an inhibitory effect on activated blood coagulation factor X (FXa), and is useful as an agent for preventing and/or treating thrombosis, wherein the pharmaceutical composition exhibits favorable dissolution properties. The present invention relates to a solid pharmaceutical composition containing a compound represented by formula (I) or a pharmacologically acceptable salt thereof, or a solvate thereof, wherein the content of the compound represented by formula (I) is 0.5% by weight or more and less than 15% by weight with respect to the total weight of the pharmaceutical composition.