Phase Change Coating Composition for Variable Data Printing

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Solution Overview

Problem

Existing overprint coatings for toner-based prints lack adequate heat and abrasion resistance, and are inefficiently applied, particularly in variable-data digital printing, where controlled application methods like ink jet printing are not effectively supported.

Innovation Solution

A phase change, curable composition comprising a curable monomer, photoinitiator, and phase change agent, which increases viscosity significantly upon cooling, allowing for precise application by ink jet printing and subsequent radiation-induced polymerization to form a robust protective coating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If known overprint coatings are applied using liquid film coating devices, then the entire surface of the image is coated, but the process is inefficient and difficult for variable-data digital printing

Engineering Contradiction:
Improvecoating efficiencyVSAvoidcontrolled application capability
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent changes the physical state parameters of the coating composition by incorporating phase change materials that transition between solid and liquid states at specific temperatures. The composition is heated above the phase change temperature to become liquid for jetting, then cools below the phase change temperature to become solid for precise positioning, enabling efficient variable-data digital printing with controlled application

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transitions of the coating composition through temperature control. The composition transitions from solid to liquid when heated above the phase change temperature for inkjet deposition, and from liquid to solid when cooled below the phase change temperature for precise positioning and rapid solidification, solving both efficiency and control requirements

Inventive Principle:
Principle #36Phase transitions

2Reliability

If conventional overprint coatings are used, then application is possible, but heat and abrasion resistance is inadequate

Engineering Contradiction:
Improveheat and abrasion resistanceVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent creates a composite coating composition by combining phase change materials with curable polymers and resins. This composite structure provides both the phase change capability for controlled application and the enhanced heat and abrasion resistance for reliable protection, while the integrated formulation simplifies the manufacturing process

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the thermal and mechanical parameters of the coating by incorporating phase change materials with specific transition temperatures and curable components. This enables the coating to achieve high heat and abrasion resistance through controlled phase transitions and curing, while maintaining ease of manufacture through a unified formulation approach

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides enhanced heat and abrasion resistance to toner images, enabling efficient and controlled application, suitable for stress-case media like flexible packaging and automobile manuals, while maintaining transparency and visibility of the image.

Implementation Method 1

phase change agent that provides the composition with an increase in viscosity of at least four orders of magnitude as the composition is cooled from a first temperature to a second temperature

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

photoinitiator that, when exposed to radiation, initiates polymerization of the curable monomer

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS7538145B2Curable phase change compositions and methods for using such compositions
Publication Date: 2009.05.26 GENESEE VALLEY INNOVATIONS LLC
  • US7538145B2 patent drawing
  • US7538145B2 patent drawing
  • US7538145B2 patent drawing

AI summary

The phase change, curable composition comprises curable monomer, photoinitiator that initiates polymerization of the curable monomer, and phase change agent that provides the composition with an increase in viscosity of at least four orders of magnitude, from a first temperature, the first temperature being from 50° C. to 130° C., to a second temperature, the second temperature being from 0° C. to 70° C., wherein the second temperature is at least 10° C. below the first temperature. A coating over an image may be applied by providing a composition comprising curable monomer at a first temperature; applying the composition over the image, the image being at a second temperature; and exposing the composition to radiation to initiate polymerization of the curable monomer. In this process, the composition has a viscosity at the second temperature that is at least four orders of magnitude greater than its viscosity at the first temperature.