Phase Change Inks with Cashew Nutshell Liquid Additives

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Solution Overview

Problem

There is a need for improved phase change inks that utilize ingredients from renewable sources, offer enhanced thermal stability, and reduce costs, while maintaining the benefits of existing phase change inks such as reduced nozzle clogging and improved dot quality in inkjet printing.

Innovation Solution

The development of phase change inks containing cashew nutshell liquid (CNSL)-derived additives, which serve as components of the ink carrier, providing enhanced thermal stability and renewable resource utilization, combined with traditional phase change ink carriers and colorants, and optionally including antioxidants for image protection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If traditional phase change ink carriers are used, then the ink provides stable phase change properties, but the thermal stability is insufficient and jetting temperatures are high

Engineering Contradiction:
Improvejetting temperatureVSAvoidenergy consumption
Core Design Contradiction:
TemperatureVSLoss of energy

Solution Approach 1:

The patent modifies the chemical composition parameters of the ink carrier by incorporating CNSL-derived additives with specific molecular structures (phenolic compounds with long alkyl chains). This changes the thermal properties of the ink, lowering the jetting temperature from typical high values to below 100°C while maintaining phase change functionality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite ink carrier system combining traditional phase change materials (waxes, fatty acids) with CNSL-derived phenolic compounds. This composite approach leverages the complementary properties of each component: the traditional materials provide phase change stability while the CNSL derivatives enhance thermal stability and reduce jetting temperature.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If renewable resources are utilized in ink composition, then environmental sustainability is improved, but the thermal stability and performance may be compromised

Engineering Contradiction:
Improvethermal stabilityVSAvoidrenewable resource utilization
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent utilizes cashew nutshell liquid, a readily available renewable resource that would otherwise be waste material. This approach replaces expensive or less sustainable traditional ink carriers with a cost-effective, environmentally friendly alternative that maintains or improves performance.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent modifies the chemical structure parameters of the CNSL-derived additives through controlled processing to optimize thermal stability. By adjusting molecular weight distribution and functional group content, the ink achieves both renewable resource utilization and enhanced thermal stability.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If ink viscosity is reduced for easier jetting, then nozzle clogging is reduced, but image quality and dot precision may deteriorate

Engineering Contradiction:
Improvenozzle clogging resistanceVSAvoiddot quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent exploits the phase transition properties of the ink carrier, which remains solid at room temperature (preventing nozzle clogging) but melts into a low-viscosity liquid at jetting temperature (enabling smooth ejection and high dot quality). The CNSL-derived additives sharpens this phase transition, creating a clear solid-liquid transition at the desired jetting temperature.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The CNSL-derived additives enhance the thermal stability and viscosity characteristics of the inks, allowing for lower jetting temperatures and energy savings, while maintaining image quality and reducing costs, thus addressing the need for improved phase change inks with renewable and cost-effective solutions.

Implementation Method 1

Phase change inks (sometimes referred to as 'hot melt inks') are in the solid phase at ambient temperature, but exist in the liquid phase at the elevated operating temperature of an ink jet printing device

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

melting the ink

Methodology Applied
Scientific EffectThermal heating: Heating

Data Source

PatentUS9234109B2Phase change inks
Publication Date: 2016.01.12 GENESEE VALLEY INNOVATIONS LLC
  • US9234109B2 patent drawing
  • US9234109B2 patent drawing
  • US9234109B2 patent drawing

AI summary

Phase change ink comprising colorant and carrier comprising additive of formulawherein A, E, G, and J are —H, —Cl, —Br, —I, —OH, —COOH, amino, alkyl, aryl, arylalkyl, alkylaryl; Z is —H, alkyl, aryl, arylalkyl, alkylaryl, —(CH2CH2O)mH,Na, K, —P(X)(OR5)(OR6) wherein X is oxygen or sulfur, or —C(═O)R7, and n is 0, 1, 2, or 3. Also, a process which comprises (1) incorporating into an ink jet printing apparatus a phase change ink as disclosed herein; (2) melting the ink; and (3) causing droplets of the melted ink to be ejected in an imagewise pattern onto a substrate.