Phase-Mask Nano-Patterning With Angle-Resolved 3D Channel Control

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Solution Overview

Problem

Conventional methods for fabricating 3D nano-structures, such as laser interference lithography and proximity-field nano-patterning (PnP), face challenges including low efficiency, high costs, and limited reproducibility and size applicability, and are restricted to forming specific symmetrical structures like body-centered-cubic or hexagonal channel structures.

Innovation Solution

A method involving a PnP process using a phase mask with an uneven lattice structure and adjusting the light-exposure angle to form nano-structures, allowing for the creation of nano-structures with channels arranged in a rectangular shape by optimizing the incidence angle of light on the photoresist film, which is not achievable with conventional methods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If laser interference lithography is used to fabricate 3D nano-structures, then periodic interference patterns can be formed, but the optical system becomes complicated and costs increase

Engineering Contradiction:
Improveperiodic interference pattern formationVSAvoidoptical system complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent extracts the essential function of laser interference lithography (forming periodic interference patterns) and separates it from the complicated optical system. By using a phase mask to generate the interference pattern directly, the complex optical components (lenses, mirrors, beam splitters) are removed, retaining only the core functionality.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses a phase mask as a physical template that copies the desired periodic pattern directly onto the photoresist film. Instead of using complex optical systems to project patterns, the phase mask serves as a reusable copy mechanism that simplifies the fabrication process while maintaining pattern accuracy.

Inventive Principle:
Principle #26Copying

2Manufacturing precision

If conventional PnP method with vertical light exposure is used, then symmetrical structures (BCC, BCT) can be formed, but the applicable structure types are limited

Engineering Contradiction:
Improvesymmetrical structure formationVSAvoidstructure type variety
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent introduces asymmetry by tilting the photoresist film at a specific angle (e.g., 54.7°) relative to the vertically incident laser beam. This breaks the symmetry of the conventional vertical exposure method, enabling the formation of non-symmetrical structures such as rectangular channel arrangements while maintaining manufacturing precision through controlled angular positioning.

Inventive Principle:
Principle #4Asymmetry

Solution Approach 2:

The patent makes the exposure geometry dynamic by allowing adjustment of the photoresist film orientation angle. This dynamic positioning capability enables switching between different structure types (symmetrical and non-symmetrical) by simply changing the film angle, thereby increasing versatility without complicating the phase mask design.

Inventive Principle:
Principle #15Dynamics

3Adaptability or versatility

If LBL deposition method is used to fabricate 3D nano-structures, then various shapes can be formed, but the process efficiency is low and costs are high

Engineering Contradiction:
Improvenano-structure shape varietyVSAvoidfabrication process efficiency
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The patent performs preliminary action by pre-forming the 3D nano-structure pattern directly in a single exposure step using the tilted photoresist film method. This eliminates the need for multiple sequential deposition layers, achieving both shape variety and high productivity by establishing the complete structure geometry in one fabrication pass.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the fabrication of nano-structures with varied channel arrangements, such as rectangular shapes, improving process suitability and device performance, and allows for the formation of structures not possible with traditional PnP methods, enhancing the versatility and efficiency of nano-device manufacturing.

Implementation Method 1

The laser beam is diffracted and divided into a plurality of laser beams when passing through the lattice structure of the phase mask. The diffraction of the laser beam may be determined or varies depending on a wavelength of the laser beam, a refractivity of the phase mask and the photoresist film, a depth of the lattice structure, a period of the lattice structure, or the like.

Methodology Applied
Scientific EffectDiffraction: Diffraction

Implementation Method 2

The laser beams interfere with one another in the photoresist film to form a 3D periodic interference pattern

Methodology Applied
Scientific EffectInterference: Interference

Data Source

PatentUS11837470B2Method of fabrication and control of nano-structure array by angle-resolved exposure in proximity-field nano patterning
Publication Date: 2023.12.05 SAMSUNG ELECTRONICS CO LTD
  • US11837470B2 patent drawing
  • US11837470B2 patent drawing
  • US11837470B2 patent drawing

AI summary

A method for fabricating a nano-structure includes: providing a phase mask having an uneven lattice structure to contact a photoresist film; exposing the photoresist film to a light through the phase mask such that the light is obliquely incident on a surface of the photoresist film; and developing the photoresist film to form a nano-structure.