Phase Separating Glass Composition for Anti-Reflective Laminate

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Solution Overview

Problem

Conventional anti-reflective (AR) glass technologies, such as coatings and etch patterning, face challenges with high costs and time requirements, and difficulty in control, necessitating the development of alternative glass compositions with improved AR properties.

Innovation Solution

A glass composition comprising specific mole percentages of SiO2, Al2O3, B2O3, R2O, MgO, CaO, and SrO, which undergo phase separation to form a porous, interconnected matrix, reducing reflection through refractive index manipulation and porosity optimization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional AR coatings are applied to glass surfaces, then reflection is reduced, but cost and processing time increase

Engineering Contradiction:
ImprovereflectionVSAvoidprocessing time
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The patent modifies the bulk glass composition parameters (adding specific oxide components) to enable inherent anti-reflective properties through phase separation, eliminating the need for separate AR coating processing steps and reducing overall processing time

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite glass structure through phase separation, forming a porous network within the glass matrix that provides anti-reflective properties, combining multiple functional characteristics in a single material system

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If conventional AR coatings are applied to glass surfaces, then reflection is reduced, but manufacturing cost increases

Engineering Contradiction:
ImprovereflectionVSAvoidmanufacturing cost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The glass composition itself provides the anti-reflective function through its inherent phase separation behavior during manufacturing, eliminating the need for separate AR coating applications and reducing manufacturing complexity and cost

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

By adjusting the chemical composition parameters of the glass melt, the invention enables self-organizing phase separation that creates anti-reflective properties without requiring additional manufacturing steps or specialized equipment

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If conventional AR coatings are applied to glass surfaces, then reflection is reduced, but control difficulty increases

Engineering Contradiction:
ImprovereflectionVSAvoidcontrol precision
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The phase separation process occurs spontaneously based on the glass composition and cooling history, providing inherent control mechanisms that eliminate the need for precise manual control of multiple coating layers and their interfaces

Inventive Principle:
Principle #25Self-service

4Object-affected harmful factors

If phase separation is induced in glass cladding layer, then anti-reflective properties are achieved, but processing temperature increases

Engineering Contradiction:
ImprovereflectionVSAvoidprocessing temperature
Core Design Contradiction:
Object-affected harmful factorsVSTemperature

Solution Approach 1:

The invention modifies the glass composition by adding specific oxide components that lower the phase separation temperature, enabling anti-reflective property formation at reduced processing temperatures compared to conventional approaches

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS20240368022A1Glass compositions and glass laminate articles comprising the same
Publication Date: 2024.11.07 CORNING INC
  • US20240368022A1 patent drawing
  • US20240368022A1 patent drawing
  • US20240368022A1 patent drawing

AI summary

A glass composition includes from 50 mol % to 80 mol % SiO2; from 5 mol % to 15 mol % Al2O3; from 10 mol % to 25 mol % B2O3; greater than or equal to 0 mol % Li2O; greater than or equal to 0 mol % Na2O; greater than or equal to 0 mol % K2O; greater than or equal to 0 mol % Rb2O; greater than or equal to 0 mol % Cs2O; from 1.5 mol % to 5 mol % MgO; from 4 mol % to 12 mol % CaO; and from 0.5 mol % to 5 mol % SrO. R2O is from 0.1 mol % to 15 mol %, R2O being the sum of Li2O, Na2O, K2O, Rb2O, and Cs2O.