Phase Transition Resistive Memory Switching

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Solution Overview

Problem

Resistive random-access memory (RRAM) devices face reliability challenges due to uncontrollable movement of individual atoms during switching mechanisms, necessitating a new switching mechanism that can reliably transform between high and low resistive states.

Innovation Solution

A resistive random-access memory (RRAM) device utilizing a phase change material, such as MoTe2, GaTe, or ReSe2, that undergoes phase transitions in response to electric fields or Joule heating, allowing for controlled switching between high and low resistive states through electric field-induced phase transitions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If valence change memory or electrochemical metallization mechanisms are used in RRAM devices, then resistive switching can be achieved, but reliability deteriorates due to uncontrollable movement of individual atoms

Engineering Contradiction:
ImprovereliabilityVSAvoiduncontrollable atom movement
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies phase transition mechanisms where a phase change material transforms between different crystalline phases (e.g., from amorphous to crystalline or between different polymorphic forms) in response to applied voltage or temperature changes. This phase transition causes a reversible change in electrical resistance, enabling reliable resistive switching without the need for individual atom migration, thereby resolving the reliability issue associated with atomic movement control

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent replaces the mechanical/chemical mechanism of individual atom movement and migration (as in VCM or ECM) with a collective phase transition mechanism. Instead of relying on controlled movement of discrete atoms, the entire material undergoes a coordinated structural transformation, substituting the problematic mechanical atomic migration with a more controllable phase change process that responds to external stimuli

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Device complexity

If conventional RRAM switching mechanisms are used, then resistive state change can be achieved, but device complexity increases due to the need for precise atomic control

Engineering Contradiction:
Improvedevice complexityVSAvoidatomic movement control
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent utilizes phase transition materials that undergo reversible structural changes between different phases with distinct electrical properties. By applying voltage or thermal stimuli, the material transitions between phases, creating high and low resistive states. This approach simplifies device structure compared to conventional methods requiring precise atomic layer control, as the phase transition occurs throughout the material bulk rather than requiring atom-by-atom manipulation

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent exploits changes in physical parameters (temperature, electric field, pressure) to induce phase transitions in the active material. By controlling these external parameters, the device can switch between resistive states without requiring complex internal atomic structures or precise atomic positioning, thereby reducing overall device complexity while maintaining switching functionality

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The phase transition-based RRAM device achieves reliable and repeatable switching between high and low resistive states, enhancing the reliability and scalability of RRAM technology for applications in neuromorphic computing and memristor-based nonvolatile logic circuits.

Implementation Method 1

The active material is a phase change material which undergoes phase transition in the presence of an electric field, Joule heating, or a combination thereof

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 2

The active material is a phase change material which undergoes phase transition in the presence of an electric field, Joule heating, or a combination thereof

Methodology Applied
Scientific EffectElectric field-induced phase transition: Electric Field

Data Source

PatentUS10505109B1Phase transition based resistive random-access memory
Publication Date: 2019.12.10 PURDUE RES FOUND
  • US10505109B1 patent drawing
  • US10505109B1 patent drawing
  • US10505109B1 patent drawing

AI summary

A resistive random access memory (Device) is disclosed. The Device includes a substrate, a first electrode formed atop the substrate, a tunneling barrier layer formed atop the first electrode, an active material formed atop the tunneling barrier layer, an isolation layer formed atop the active material, and a second electrode formed atop the isolation layer, the first electrode and the second electrode provide electrical connectivity to external components, where the active material is a phase change material which undergoes phase transition in the presence of an electric field, Joule heating, or a combination thereof.