Phenanthroline Organic Compound for OLED Electron Transport

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Solution Overview

Problem

Typical charge generation layers in tandem OLEDs suffer from reduced thermal and electrical stability, leading to deterioration and decreased lifespan due to metal diffusion and inefficient electron injection, especially when doped with alkali metals.

Innovation Solution

An organic compound with a phenanthroline moiety substituted with aromatic rings is used as a charge generation and electron transport material, providing improved thermal stability and electron injection properties by forming a gap state with alkali metal or alkali earth metal compounds, reducing energy level differences and preventing diffusion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If typical charge generation layer materials are doped with metal to improve electrical conductivity, then electron injection efficiency is improved, but thermal stability deteriorates causing metal diffusion and reduced lifespan

Engineering Contradiction:
Improveelectron injection efficiencyVSAvoidthermal stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent introduces an organic compound as an intermediary material between the metal dopant and the charge generation layer. This compound mediates the interaction by providing a stable matrix that prevents direct metal diffusion while maintaining electrical conductivity through the organic compound's inherent properties and controlled doping mechanisms

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs composite materials by combining organic compounds with specific molecular structures (containing nitrogen-containing heterocyclic groups) with metal dopants in controlled ratios. This composite approach creates a material system where the organic component provides thermal stability and structural integrity while the metal component provides electrical conductivity, resolving the contradiction between these two properties

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If tandem OLED structure is used to achieve long lifespan and white light emission, then display performance is improved, but device complexity increases

Engineering Contradiction:
ImprovelifespanVSAvoidstructure complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent applies universality by designing charge generation layer materials that perform multiple functions simultaneously. The organic compound with nitrogen-containing heterocyclic groups provides charge generation, charge transport, and energy level matching functions in a single material system, reducing the need for separate functional layers and simplifying the overall tandem OLED structure while maintaining long lifespan performance

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic compound enhances the lifespan and efficiency of OLEDs by maintaining thermal stability, reducing driving voltage, and ensuring efficient electron transfer and injection, while preventing alkali metal diffusion into the P-type charge generation layer.

Implementation Method 1

providing improved thermal stability and electron injection properties by forming a gap state with alkali metal or alkali earth metal compounds

Methodology Applied
Scientific EffectGap state formation:

Implementation Method 2

preventing diffusion

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS11258019B2Organic compound, organic light emitting diode including the same, and organic light emitting display
Publication Date: 2022.02.22 LG DISPLAY CO LTD
  • US11258019B2 patent drawing
  • US11258019B2 patent drawing
  • US11258019B2 patent drawing

AI summary

Disclosed herein is an organic compound, an organic light emitting diode including the same, and an organic light emitting display. The organic compound according to the present disclosure is a phenanthroline compound represented by the following Formula 1, which is used as an electron transport material of an organic light emitting diode. The phenanthroline compound can increase lifespan of the organic light emitting diode while reducing driving voltage of the organic light emitting diode.