Phenol-Functional Polyamide Adhesive for Thin Semiconductor Die Bonding

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Solution Overview

Problem

Conventional die-attach pastes face challenges in bonding thin semiconductor dies, particularly in stacked packages, due to their inability to provide adequate mechanical strength and compatibility with the increasing demand for reduced package size in the semiconductor industry.

Innovation Solution

The development of low molecular weight, phenol-functional polyamides as film-forming adhesives that can be cured with or without a catalyst, offering toughness and non-tacky properties, which convert to low viscosity fluids for effective bonding of silicon devices and substrates, and provide reactive sites for epoxy compounds to enhance the adhesive properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional die-attach pastes are used, then bonding of semiconductor dies is achieved, but mechanical strength and compatibility with reduced package size are insufficient

Engineering Contradiction:
Improvemechanical strengthVSAvoidcompatibility with reduced package size
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent changes the molecular weight parameter of the polyamide from conventional high molecular weight to low molecular weight (average molecular weight of about 1,000 to 10,000), which fundamentally alters the material's bonding characteristics and enables effective adhesion to thin semiconductor dies while maintaining mechanical strength

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite adhesive system combining low molecular weight phenol-functional polyamide with epoxy compounds, where the polyamide provides mechanical strength and the epoxy provides chemical reactivity and adhesion, achieving both high strength and compatibility with thin dies

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If low molecular weight phenol-functional polyamides are used, then film-forming properties and bonding effectiveness are improved, but curing requirements and process complexity increase

Engineering Contradiction:
Improvefilm-forming propertiesVSAvoidcuring process complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The low molecular weight phenol-functional polyamide contains inherent reactive phenolic groups that enable self-curing through reaction with epoxy compounds without requiring external catalysts or complex curing systems, simplifying the overall process while maintaining effective bonding

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent utilizes the low molecular weight parameter (average molecular weight of about 1,000 to 10,000) to achieve optimal balance between film-forming properties and curing behavior, where the material remains processable yet cures effectively through its inherent reactive groups

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The described adhesive compositions provide a robust and flexible bonding solution for thin semiconductor dies, ensuring effective adhesion and retention of mechanical properties even at high temperatures, suitable for various electronic packaging applications.

Implementation Method 1

The phenolic residues within the backbone of these oligomers provide reactive sites for the cure of epoxy compounds

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

Heating these compounds results in their conversion to relatively low viscosity fluids, which are capable of fully wetting the back of silicon devices and the substrates to which they are being bonded

Methodology Applied
Scientific EffectThermal energy: Heating

Implementation Method 3

The phenolic residues within the backbone of these oligomers provide reactive sites for the cure of epoxy compounds

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS7678879B2Adhesive composition of phenol-functional polyamides
Publication Date: 2010.03.16 DESIGNER MOLECULES INC
  • US7678879B2 patent drawing
  • US7678879B2 patent drawing
  • US7678879B2 patent drawing

AI summary

The invention is based on the discovery that the compounds and compositions described herein are useful as film-forming adhesives for use in a variety of applications, including, for example, adhesive tapes for the electronic packaging industry. The invention compositions described herein can be cured in a variety of ways with or without a catalyst.