Phenolic-Polyurethane Binders for Durable Abrasive Articles

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Solution Overview

Problem

There is a need to improve the cost, performance, and/or life of abrasive articles such as coated abrasives and nonwoven abrasives.

Innovation Solution

The use of a binder material comprising a cured reaction product of phenolic resin and an aqueous dispersion of polyurethane, with specific weight ratios, to secure abrasive particles to a substrate, enhancing toughness and brittleness/stiffness properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional binder materials are used to secure abrasive particles to the substrate, then the abrasive article can be manufactured with standard properties, but the toughness and brittleness/stiffness properties are insufficient

Engineering Contradiction:
Improvetoughness and brittleness/stiffnessVSAvoiddurability and performance characteristics
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies composite materials by combining phenolic resin and polyurethane dispersion in a binder system. This composite binder material integrates the toughness of polyurethane with the stiffness and heat resistance of phenolic resin, achieving balanced mechanical properties that resolve the contradiction between toughness and brittleness/stiffness requirements for abrasive articles.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs parameter changes by systematically varying the ratio of phenolic resin to polyurethane dispersion (from 90:10 to 10:90) to optimize the balance between toughness and brittleness/stiffness. This parametric approach allows tuning of the binder properties to achieve desired durability and performance characteristics for different abrasive application requirements.

Inventive Principle:
Principle #35Parameter changes

2Strength

If phenolic resin and polyurethane dispersion are combined in specific ratios, then toughness and brittleness/stiffness are enhanced, but the binder formulation complexity increases

Engineering Contradiction:
Improvetoughness and brittleness/stiffnessVSAvoidbinder formulation complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent manages formulation complexity through systematic parameter changes by defining specific ratio ranges (90:10 to 10:90 phenolic resin to polyurethane) rather than exploring unlimited compositional space. This parametric framework simplifies the formulation process while still achieving enhanced toughness and brittleness/stiffness properties.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The phenolic/polyurethane binder materials provide improved durability and performance characteristics to abrasive articles, enhancing their effectiveness in abrading and finishing applications.

Implementation Method 1

the at least one binder material comprises a cured reaction product of components comprising: a) at least one phenolic resin; and b) an aqueous dispersion of at least one polyurethane

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

the curable make resin is at least partially cured (that is, crosslinked) to adhere the abrasive particles to the backing

Methodology Applied
Scientific EffectCrosslinking:

Implementation Method 3

the abrading action of the belt on a workpiece (e.g., wood) increases the load on the drive motor used to drive the belt

Methodology Applied
Scientific EffectAbrasion: Abrasion

Data Source

PatentEP3924149B1Abrasive articles and methods of making and using the same
Publication Date: 2025.07.09 3M INNOVATIVE PROPERTIES CO
  • EP3924149B1 patent drawingFigure 1~3B

AI summary

An abrasive article comprises abrasive particles secured to a substrate by at least one binder material. The at least one binder material comprises a cured reaction product of components comprising: a) at least one phenolic resin; and b) an aqueous dispersion of at least one polyurethane, wherein, based on the total solids weight of components a) and b), the components comprise 56 to 91 percent by weight of component a) and 44 to 9 percent by weight of component b). Methods of making and using the abrasive articles are also disclosed.