Phenolic Rubber Composition for Sulfur-Free Metal Adhesion

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Solution Overview

Problem

Existing rubber compositions for pneumatic tire reinforcement plies require high sulfur and zinc oxide content, which pose challenges during production due to premature crosslinking, and alternative compositions with good adhesion to metallic reinforcing elements are sought.

Innovation Solution

A rubber composition based on diene elastomer, a reinforcing filler, and a crosslinking system using radical polymerization initiators, incorporating a phenolic compound with specific substituents and optionally sugars, without sulfur, to enhance adhesion to metallic surfaces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high sulfur and zinc oxide content is used in the rubber compound, then good adhesion to metallic reinforcing elements is achieved, but premature crosslinking occurs during production

Engineering Contradiction:
Improveadhesion to metallic reinforcing elementsVSAvoidproduction process control
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters of the rubber compound by incorporating specific phenolic compounds (such as gallic acid, protocatechuic acid, and their derivatives) that enable adhesion to metallic surfaces without requiring high sulfur and zinc oxide content. This parameter change allows the compound to achieve good adhesion while avoiding premature crosslinking during production, as the phenolic compounds provide an alternative adhesion mechanism that does not trigger early vulcanization.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If sulfur-based crosslinking system is used to achieve good adhesion, then adhesion performance is improved, but production constraints increase due to premature crosslinking

Engineering Contradiction:
Improveadhesion performanceVSAvoidproduction process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts the essential adhesion function from the sulfur-based crosslinking system by identifying and isolating the specific phenolic compounds that provide adhesion to metallic surfaces. By taking out this specific adhesion-providing component (phenolic compounds with particular molecular structures and functional groups), the patent achieves good adhesion performance without incorporating the sulfur-based crosslinking system that causes production constraints and premature crosslinking.

Inventive Principle:
Principle #2Taking out (Extraction)

3Ease of manufacture

If alternative rubber compositions without sulfur are formulated, then production constraints are reduced, but adhesion to metallic reinforcing elements may be compromised

Engineering Contradiction:
Improveproduction process flexibilityVSAvoidadhesion to metallic reinforcing elements
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent introduces specific phenolic compounds as intermediary substances that mediate the adhesion between the rubber compound and metallic reinforcing elements. These phenolic compounds (including gallic acid, protocatechuic acid, and their derivatives with specific molecular weights and functional groups) act as chemical intermediaries that bond to both the rubber matrix and the metal surface, providing effective adhesion without requiring sulfur-based crosslinking systems, thus maintaining production flexibility while ensuring reliable adhesion.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves excellent adhesion to metallic substrates without sulfur, reducing production constraints and maintaining performance.

Implementation Method 1

a crosslinking system based on at least one or more radical polymerization initiators

Methodology Applied
Scientific EffectRadical polymerization: Photopolymerisation

Implementation Method 2

The composition achieves excellent adhesion to metallic substrates without sulfur

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentEP4168255B1Elastomeric composition comprising a phenolic compound and a compound from the monosaccharide family
Publication Date: 2026.03.04 MICHELIN & CO (CIE GEN DES ESTAB MICHELIN)
  • EP4168255B1 patent drawing
  • EP4168255B1 patent drawing
  • EP4168255B1 patent drawing

AI summary

The invention relates to a rubber composition based on at least one elastomer, at least one phenolic compound and at least one compound from the monosaccharide family, the aromatic ring of said phenolic compound being substituted with at least one hydrocarbon substituent, the molar mass of said phenolic compound being at most equal to 1000 g/mol.