Phenoxy-Epoxy Antistatic Label Coating for High Temperature

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Solution Overview

Problem

Existing antistatic labels have low durability and poor temperature resistance, failing to provide effective electrostatic dissipative properties and printability in high-temperature applications such as automotive and aeronautic industries.

Innovation Solution

A phenoxy-epoxy resin system with dispersed carbon nanotubes, an isocyanate crosslinking agent, and a metal catalyst is used to create an electrostatic dissipative coating composition for pressure-sensitive adhesive labels, which includes a polymer film substrate with an antistatic base coat, enhancing durability and temperature resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a polyimide film with an antistatic base coat is used, then electrostatic dissipative properties are provided, but durability and temperature resistance are poor

Engineering Contradiction:
Improveelectrostatic dissipative propertiesVSAvoiddurability
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent uses a composite coating system consisting of an antistatic base coat layer and a clear topcoat layer. The base coat contains conductive materials (carbon black, metal particles, or conductive polymers) dispersed in a thermoplastic adhesive matrix, while the topcoat provides protective properties. This composite structure combines the electrostatic dissipative function of the base coat with the durability and temperature resistance of the topcoat, resolving the contradiction between providing electrostatic properties and achieving long-term durability.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a polyimide film with an antistatic base coat is used, then electrostatic dissipative properties are provided, but temperature resistance is poor

Engineering Contradiction:
Improveelectrostatic dissipative propertiesVSAvoidtemperature resistance
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The clear topcoat layer is formulated with high-temperature resistant thermoplastic polymers (polyethylene terephthalate, polyacrylic acid, polyacrylamide, or polyvinylidene fluoride) that can withstand temperatures up to 200°C or higher. This topcoat protects the underlying antistatic base coat from thermal degradation, allowing the label to maintain its electrostatic dissipative properties at elevated temperatures while achieving the required temperature resistance for automotive and industrial applications.

Inventive Principle:
Principle #40Composite materials

3Reliability

If a surface coating composition is applied, then electrostatic discharge properties are achieved, but printability may be compromised

Engineering Contradiction:
Improveelectrostatic discharge propertiesVSAvoidprintability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent creates a multi-layer structure where the antistatic base coat provides electrostatic dissipative properties while the clear topcoat provides a uniform, smooth surface optimized for printability. The topcoat acts as a separate functional layer that does not interfere with the printing process, allowing labels to be printed with various inks and printing systems while maintaining the underlying electrostatic properties. This layering approach allows each layer to optimize its specific function without compromising the other.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves electrostatic discharge properties within the desired range, maintains low voltage charging, and resists degradation at high temperatures, ensuring effective electrostatic dissipation and printability in various applications.

Implementation Method 1

Carbon nanotubes are dispersed in the phenoxy-epoxy resin system

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

The coating composition includes at least one isocyanate crosslinking agent

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 3

The coating composition includes at least one metal catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS10689548B2Electrostatic dissipative surface coating and high temperature label employing same
Publication Date: 2020.06.23 POLYONICS CORP
  • US10689548B2 patent drawing

AI summary

An electrostatic dissipative coating composition comprises a phenoxy-epoxy resin system comprising from 40-80 parts by weight to 5-20 parts by weight of an epoxy resin. Carbon nanotubes are dispersed in the phenoxy-epoxy resin system. The coating composition includes at least one isocyanate crosslinking agent and at least one metal catalyst. In a further aspect, a label construction comprising the electrostatic dissipative coating composition is provided.