Phenylanthracene Host Compound for Blue OLED Efficiency

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Solution Overview

Problem

Current organic light emitting diodes (OLEDs) face challenges with low efficiency and short lifetime, despite advancements in technology, and existing host materials for the emission layer, such as phenylanthracene derivatives, do not adequately improve current efficiency and luminous efficacy.

Innovation Solution

A novel compound represented by Formula (I) is introduced, which can be used as a host material in OLEDs, specifically for the emission layer, to enhance efficiency, with specific structural parameters allowing for improved performance as a blue host material.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If phenylanthracene derivatives are used as host materials in OLEDs, then blue emission is achieved, but current efficiency and luminous efficacy remain low

Engineering Contradiction:
Improvecurrent efficiencyVSAvoidluminous efficacy
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent modifies the molecular structure of host materials by introducing specific substituents (naphthyl, phenyl, anthryl groups) at defined positions of the phenylanthracene core, and adjusts molecular weight and structural parameters to optimize energy transfer efficiency and electroluminescence performance, thereby improving both current efficiency and luminous efficacy simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite host materials combining phenylanthracene derivatives with dopant materials (such as fluorescent or phosphorescent emitters) to create emission layers with enhanced performance. The composite structure enables efficient energy transfer from host to dopant while maintaining structural stability and improving overall device efficiency

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional host materials are used in OLEDs, then device fabrication is straightforward, but efficiency and lifetime are insufficient

Engineering Contradiction:
Improvefabrication simplicityVSAvoiddevice efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent optimizes molecular weight, structural symmetry, and substituent positions of host materials to achieve optimal balance between ease of deposition and device performance. The modified structures maintain compatibility with conventional vacuum deposition and solution processing methods while significantly improving efficiency and lifetime

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If existing host materials are used for blue OLEDs, then device structure is maintained, but luminous efficacy needs improvement

Engineering Contradiction:
Improvestructural stabilityVSAvoidluminous efficacy
Core Design Contradiction:
Stability of the object's compositionVSLoss of energy

Solution Approach 1:

The patent introduces specific structural modifications to phenylanthracene derivatives, including controlled substitution at 2,7-positions with naphthyl or phenyl groups, and adjusts molecular weight to optimize rigid planar structure. These changes enhance structural stability while improving triplet energy levels and reducing non-radiative decay, thereby increasing luminous efficacy

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the novel compound as a host material in OLEDs results in improved current efficiency, luminous efficacy, and external quantum efficiency compared to commercial host materials, reducing driving voltage and enhancing overall performance.

Implementation Method 1

Recombination of the electrons and the holes occurs in the EL to generate excitons, thereby emitting a light when the excitons decay from excited state to ground state

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11038123B2Compound and organic electronic device using the same
Publication Date: 2021.06.15 NICHEM FINE TECH CO LTD
  • US11038123B2 patent drawing
  • US11038123B2 patent drawing
  • US11038123B2 patent drawing

AI summary

Provided are a novel compound and an organic electronic device using the same. The novel compound is represented by the following Formula (I):wherein n1, n2, m1, m2, m3, and g1 are each independently an integral, and the sum of n1 and n2 is 2 or 3; Ant isL1, L2 and L3 are each independently an arylene group; G1 and G2 are each independently selected from the group consisting of: a hydrogen atom, a deuterium atom, an alkyl group, an alkenyl group, an alkynyl group, a cycloalkyl group, a heterocycloalkyl group, an aryl group, and a heteroaryl group; and R1 and R2 are each independently selected from the group consisting of: a hydrogen atom, a deuterium atom, an alkyl group, and an aryl group.