Phosphate-Modified Self-Dispersible Pigment Ink for High Optical Density

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Solution Overview

Problem

Current water-based pigment inks for ink-jet recording face challenges in achieving improved optical density and chromaticness, with existing solutions not adequately addressing these requirements.

Innovation Solution

The use of a water-based ink containing self-dispersible pigments modified with phosphate groups and dextran or its derivatives, which enhances optical density and chromaticness by improving pigment dispersion and interaction with the recording medium.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If water-dispersible polymer is contained in water-based pigment ink to improve optical density and chromaticness, then optical density and chromaticness are improved, but further improvement is still demanded

Engineering Contradiction:
Improveoptical densityVSAvoidimprovement sufficiency
Core Design Contradiction:
Illumination intensityVSProductivity

Solution Approach 1:

The patent modifies the pigment surface chemistry by introducing phosphate groups to create self-dispersible pigments. This chemical parameter change enables the pigment to autonomously disperse in water without requiring additional water-dispersible polymers, achieving superior optical density and chromaticness while simplifying the ink formulation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite pigment structure by combining colorant particles with phosphate group modifiers on the surface. This composite material exhibits both coloration properties and self-dispersion capabilities, eliminating the need for separate dispersing agents and achieving enhanced optical performance.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If treatment agent is combined with water-based ink to unstabilize dissolved or dispersed state of colorant, then optical density is improved, but further improvement is demanded and chromaticness is not sufficiently improved

Engineering Contradiction:
Improveoptical densityVSAvoidimprovement sufficiency
Core Design Contradiction:
Illumination intensityVSProductivity

Solution Approach 1:

Instead of using treatment agents to destabilize colorant as in conventional approaches, the patent inverts the approach by creating pigments that inherently stabilize through self-dispersion. The phosphate-modified pigments automatically achieve optimal dispersion state upon contact with water, eliminating the need for separate treatment agents and achieving both higher optical density and chromaticness.

Inventive Principle:
Principle #13The other way round (Inversion)

3Ease of manufacture

If conventional water-based pigment ink is used, then basic recording function is achieved, but optical density and chromaticness are not sufficiently improved

Engineering Contradiction:
Improveink formulation simplicityVSAvoidoptical density
Core Design Contradiction:
Ease of manufactureVSIllumination intensity

Solution Approach 1:

The phosphate-modified pigments are self-service in nature, automatically dispersing in water without requiring external dispersing agents or complex treatment processes. This self-dispersion capability simplifies ink formulation while achieving superior optical density and chromaticness, making the manufacturing process both easier and more effective.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in significantly improved optical density and chromaticness in ink-jet recordings, with the water-based ink set effectively stabilizing the pigment dispersion and enhancing storage stability and vaporization characteristics.

Implementation Method 1

self-dispersible pigment modified with phosphate group

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Implementation Method 2

self-dispersible pigment modified with phosphate group

Methodology Applied
Scientific EffectSteric hindrance:

Implementation Method 3

at least one of dextran and a derivative thereof

Methodology Applied
Scientific EffectSteric stabilization:

Data Source

PatentUS9340689B2Water-based ink for ink-jet recording, water-based ink set for ink-jet recording, and treatment agent
Publication Date: 2016.05.17 BROTHER KOGYO KK
  • US9340689B2 patent drawing
  • US9340689B2 patent drawing
  • US9340689B2 patent drawing

AI summary

A water-based ink for ink-jet recording includes a self-dispersible pigment which is modified with phosphate group, at least one of dextran and a derivative thereof, and water.